[Fe(C₅H₅)(PC₂(C₆H₅)2C₆H₈)]

Base Information

• Chemical Name: [Fe(C₅H₅)(PC₂(C₆H₅)2C₆H₈)]
• CAS No.: 869373-35-3
• Molecular Formula: C₂₅H₂₃FeP
• Molecular Weight: 410.278
• Mol file: 869373-35-3.mol

Synonyms:

Chemical Property of [Fe(C₅H₅)(PC₂(C₆H₅)2C₆H₈)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Fe(C₅H₅)(PC₂(C₆H₅)2C₆H₈)]

There total 3 articles about [Fe(C₅H₅)(PC₂(C₆H₅)2C₆H₈)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

[(η6-p-xylene)(η5-cyclopentadienyl)iron(II)](hexafluorophosphate) + 2,2',5,5'-tetraphenyl-1,1'-bisphosphole (705288-11-5) → [Fe(C5H5)(PC2(C6H5)2C6H8)] (869373-35-3)

Guidance literature:

With Li; In tetrahydrofuran; under Ar, Schlenk techniques; Li added to soln. 1,1'-diphosphole in THF at room temp., mixt. stirred at room temp. for 4 h, Fe compd. added, mixt. stirred for 3 h; soln. filtered through basic alumina, filtrate evapd. under vac., crystn. from pentane;

DOI:10.1021/om050593s

Reference yield: 30.0%

[(η6-p-xylene)(η5-cyclopentadienyl)iron(II)](hexafluorophosphate) + 1,8-diphenyl-1,7-octadiyne (13225-62-2) + phosphorus tribromide (7789-60-8) → [Fe(C5H5)(PC2(C6H5)2C6H8)] (869373-35-3)

Guidance literature:

With n-butyllithium; ZrCl₂(C₅H₅)2; Li; In tetrahydrofuran; hexane; under Ar; n-BuLi/hexane added to soln. of diyne and ZrCp2Cl2 in THF at -78°C, warmed to room temp., stirred for 15 h, PBr3 added at -78°C, stirred at room temp. for 4 h, Li added, stirred for 4 h, Fe complex added, mixt. stirred overnight; soln. filtered through basic alumina, filtrate evapd. under vac., residue extd. with pentane, crystn. at room temp.;

DOI:10.1021/om050593s

Reference yield: 28.0%

iron(dichloride)*1.5(tetrahydrofuran) + 1,8-diphenyl-1,7-octadiyne (13225-62-2) + phosphorus tribromide (7789-60-8) → [Fe(C5H5)(PC2(C6H5)2C6H8)] (869373-35-3)

Guidance literature:

With n-butyllithium; ZrCl₂(C₅H₅)2; Li; In tetrahydrofuran; hexane; under Ar; n-BuLi/hexane added to soln. of diyne and ZrCp2Cl2 in THF at -78°C, warmed to room temp., stirred for 15 h, PBr3 added at -78°C, stirred at room temp. for 4 h, Li added, stirred for 4 h, Fe compd. added, mixt. stirred overnight; soln. filtered through basic alumina, filtrate evapd. under vac., residue extd. with pentane, crystn. at room temp.;

DOI:10.1021/om050593s

upstream raw materials:

1,8-diphenyl-1,7-octadiyne

phosphorus tribromide

2,2',5,5'-tetraphenyl-1,1'-bisphosphole