1,7-C₂B₁₀H₁₁-1-CH₂C₆H₅

Base Information

• Chemical Name: 1,7-C₂B₁₀H₁₁-1-CH₂C₆H₅
• CAS No.: 65063-00-5
• Molecular Formula: C₉H₁₈B₁₀
• Molecular Weight: 234.352
• Mol file: 65063-00-5.mol

Synonyms:

Chemical Property of 1,7-C₂B₁₀H₁₁-1-CH₂C₆H₅

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,7-C₂B₁₀H₁₁-1-CH₂C₆H₅

There total 2 articles about 1,7-C₂B₁₀H₁₁-1-CH₂C₆H₅ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 42.0%

1,7-dicarba-closo-dodecaborane(12) (16986-24-6) + benzyl chloride (100-44-7) + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1) → 1,7-C2B10H11-1-CH2C6H5 (65063-00-5)

Guidance literature:

With n-butyllithium; In diethyl ether; addn. of 20mmol BuLi in C6H6 to a soln. of 20ml carborane in ether, refluxing for 1h, dropwise addn. of 20mmol C6H5CH2Cl in 20ml ether, refluxing for 3h; diln. with 10ml H2O, separation of organic layer, drying over CaCl2, evapn., sublimation in vac., distn. in vac., elem. anal.;

DOI:10.1007/BF00956366

Reference yield:

Na{1,7-C2B10H11} (56328-11-1) + benzyl chloride (100-44-7) → 1,7-C2B10H11-1-CH2C6H5 (65063-00-5)

Guidance literature:

Reference yield:

1,7-C2B10H11-1-CH2C6H5 (65063-00-5) + acetyl chloride (75-36-5) → 1,7-C2B10H11-1-(CH2C6H4-4'-COCH3) (65062-90-0)

Guidance literature:

upstream raw materials:

1,7-dicarba-closo-dodecaborane⁽¹²⁾

benzyl chloride

benzene

Na{1,7-C₂B₁₀H₁₁}

Downstream raw materials:

1,7-C₂B₁₀H₁₁-1-(CH₂C₆H₄-4'-COCH₃)