methyl 3β,4β-dihydroxy-5β-cyclohex-1-ene-1-carboxylate

Base Information

Chemical Name:methyl 3β,4β-dihydroxy-5β-cyclohex-1-ene-1-carboxylate
CAS No.:134039-36-4
Molecular Formula:C₂₁H₂₁N₃O₁₂S₂
Molecular Weight:571.543
Hs Code.:

methyl 3β,4β-dihydroxy-5β-<N,N-di(p-nitrobenzenesulphonyl)aminomethyl>cyclohex-1-ene-1-carboxylate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of methyl 3β,4β-dihydroxy-5β-cyclohex-1-ene-1-carboxylate

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Technology Process of methyl 3β,4β-dihydroxy-5β-cyclohex-1-ene-1-carboxylate

There total 11 articles about methyl 3β,4β-dihydroxy-5β-cyclohex-1-ene-1-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 16.0%

: 134039-35-3
methyl 5-cyclohexa-1,3-diene-1-carboxylate

: 134039-37-5
methyl 1,2-dihydroxy-5-cyclohex-3-ene-1-carboxylate

: 134039-36-4,134107-76-9
methyl 3α,4α-dihydroxy-5β-cyclohex-1-ene-1-carboxylate

: 134039-36-4,134107-76-9
methyl 3β,4β-dihydroxy-5β-cyclohex-1-ene-1-carboxylate

Guidance literature:: With osmium(VIII) oxide;
DOI:10.1016/S0040-4039(00)92128-2

Reference yield: 16.0%

: 134039-35-3
methyl 5-cyclohexa-1,3-diene-1-carboxylate

: 134039-37-5
methyl 1,2-dihydroxy-5-cyclohex-3-ene-1-carboxylate

: 134039-36-4,134107-76-9
methyl 3α,4α-dihydroxy-5β-cyclohex-1-ene-1-carboxylate

: 134039-36-4,134107-76-9
methyl 3β,4β-dihydroxy-5β-cyclohex-1-ene-1-carboxylate

Guidance literature:: With osmium(VIII) oxide;
DOI:10.1016/S0040-4039(00)92128-2

Reference yield:

: 134039-44-4
methyl 5-(aminomethyl)cyclohexa-1,3-diene-1-carboxylate

: 134039-36-4,134107-76-9
methyl 3α,4α-dihydroxy-5β-cyclohex-1-ene-1-carboxylate

Guidance literature:: Multi-step reaction with 3 steps

1: 63 percent / Et₃N / tetrahydrofuran / 40 h / 20 °C

2: 1.) NaH / 1.) DMF, 20 deg C, 1 h, 2.) 1.5 h

3: 16 percent / N-methylmorpholine N-oxide / OsO₄ / acetone; H₂O; 2-methyl-propan-2-ol / 24 h / 20 °C

With sodium hydride; 4-methylmorpholine N-oxide; triethylamine; osmium(VIII) oxide; In tetrahydrofuran; water; acetone; tert-butyl alcohol;
DOI:10.1016/S0040-4020(01)89449-7