trans-PdMePh(PEt₃)2

Base Information

Chemical Name:trans-PdMePh(PEt₃)2
CAS No.:116244-36-1
Molecular Formula:C₁₉H₃₈P₂Pd
Molecular Weight:434.878
Hs Code.:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of trans-PdMePh(PEt₃)2

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Technology Process of trans-PdMePh(PEt₃)2

There total 3 articles about trans-PdMePh(PEt₃)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 38.0%

: 15697-59-3
trans-PdClPh(PEt₃)2

: 116244-36-1
trans-PdMePh(PEt₃)2

Guidance literature:: With methyllithium; In diethyl ether; byproducts: LiCl; under N2, Ar or vac.; addn. of Et2O soln. of MeLi to mixt. of trans-PdPhCl(PEt3)2 and Et2O at -70°C; stirred 2h at -10 to 0°C; addn. of Me3SiCl at -30°C; concd.; addn. of hexane (-70°C, pptn. of LiCl); filtered at -40°C; concn. at -10°C; recrystn. (cold Et2O); elem. anal.;
DOI:10.1021/om00103a023

Reference yield:

: 70774-40-2,63686-70-4
trans-iodo(phenyl)bis(triethylphosphine)palladium

: 917-54-4
methyllithium

: 116244-36-1
trans-PdMePh(PEt₃)2

Guidance literature:: In tetrahydrofuran; under N2, to mixt. of PhPdI(PEt3)2 and THF cooled to -78°C addedTHF soln. of MeLi (1 equiv.), stirred for 10 min at -78°C and then for 1 h at room temp.; not isolated, detected by NMR;
DOI:10.1016/0022-328X(87)80048-7