Technology Process of RuCl3(C5H3N(C3H2(C6H5)N2)2)
There total 1 articles about RuCl3(C5H3N(C3H2(C6H5)N2)2) which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
In
2-ethoxy-ethanol;
refluxing of RuCl3*3H2O and the substituted pyridine in ethylene glycol monoethyl ether for 3 h; cooling to room temp.; performed under N2;; the ppt. was vac. filtered, washed with abs. ethanol and diethyl ether, and dried in air;;
DOI:10.1039/DT9930001563
- Guidance literature:
-
With
triethylamine;
In
dichloromethane;
addn. of 1.5 equivalents of P(CH3)3 and triethylamine to a suspension of the Ru(III) complex in CH2Cl2; refluxing for 10-24 h; performed under N2;; the ppt. was vac. filtered, washed with abs. ethanol and diethyl ether and purified, if necessary, by chromy. (basic Al2O3, 2% CH3OH/CH2Cl2); evapn.; dissolving in CH2Cl2 and dropwise addn. into hexanes;;
DOI:10.1039/DT9930001563
- Guidance literature:
-
With
zinc amalgam; NaClO4;
In
dichloromethane;
Irradiation (UV/VIS); addn. of 4.5-7 equivs. of P(CH3)3 to the Ru(III) complex in CH2Cl2; addn. of Zn/Hg amalgam; refluxing for 24 h; irradiation (120 W) for several days; filtration; evapn. to dryness; dissolving in ethanol/H2O and addn. of solid NaClO4; performed under N2;; the ppt. was vac. filtered and washed with a minimum amt. of H2O; chromy. (Al2O3, acetone); evapn. to dryness; dissolving in acetone; the soln. was titurated into O(C2H5)2; the ppt. was washed with O(C2H5)2 and dried in air; elem. anal.;;
DOI:10.1039/DT9930001563
