[HC(C(Me)N(2,6-(i)Pr2C6H3))2]Al(SH)(μ-O)P(OEt)2

Base Information

• Chemical Name: [HC(C(Me)N(2,6-(i)Pr2C6H3))2]Al(SH)(μ-O)P(OEt)2
• CAS No.: 960589-98-4
• Molecular Formula: C₃₃H₅₂AlN₂O₃PS
• Molecular Weight: 614.809
• Mol file: 960589-98-4.mol

Synonyms:

Chemical Property of [HC(C(Me)N(2,6-(i)Pr2C6H3))2]Al(SH)(μ-O)P(OEt)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [HC(C(Me)N(2,6-(i)Pr2C6H3))2]Al(SH)(μ-O)P(OEt)2

There total 1 articles about [HC(C(Me)N(2,6-(i)Pr2C6H3))2]Al(SH)(μ-O)P(OEt)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

[HC(C(Me)N(2,6-(i)Pr2C6H3))2]Al(SH)2 (501081-97-6) + phosphonic acid diethyl ester (762-04-9) → [HC(C(Me)N(2,6-(i)Pr2C6H3))2]Al(SH)(μ-O)P(OEt)2 (960589-98-4) + (HC(C(Me)N(2,6-(i)Pr2C6H3)2)Al(OEt)(μ-O)P(OEt)2 + (HC(C(Me)N(2,6-(i)Pr2C6H3)2)Al(SH)(μ-O)P(S)(OEt)2

Guidance literature:

In tetrahydrofuran; under N2 atm. (EtO)2P(O)H in THF was added dropwise to soln. Al complex in THF at -78°C over 35 min, allowed to warm to roomtemp. and stirred for 5 h; volatiles were removed in vacuo; elem. anal.;

DOI:10.1021/ic701614c

Reference yield: 62.0%

[HC(C(Me)N(2,6-(i)Pr2C6H3))2]Al(SH)(μ-O)P(OEt)2 (960589-98-4) + trimethyl gallium (1445-79-0) → [κ2-P,S-((HC((C(CH3)N(C6H3(CH(CH3)2)2))2))Al(μ-S)(μ-O)P(OEt2]GaMe2

Guidance literature:

In toluene; N2, standard Schlenk and glove box techniques; Al-compd. in toluene cooled to -78°C, GaMe3 in toluene added, warmed to ambient temp., stirred for 3 h; volatiles removed in vac., rinsed with cold hexane, dried in vac., elem.anal.;

DOI:10.1080/15533170701675162

upstream raw materials:

[HC(C(Me)N(2,6-(i)Pr₂C₆H₃))2]Al(SH)2

phosphonic acid diethyl ester