trans-bis{1,2-bis(dimethylphosphino)ethane}chloro(dinitrogen)iron(II) tetraphenylborate

Base Information

Chemical Name:trans-bis{1,2-bis(dimethylphosphino)ethane}chloro(dinitrogen)iron(II) tetraphenylborate
CAS No.:130172-25-7
Molecular Formula:C₁₂H₃₂ClFeN₂P₄*C₂₄H₂₀B
Molecular Weight:738.828
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of trans-bis{1,2-bis(dimethylphosphino)ethane}chloro(dinitrogen)iron(II) tetraphenylborate

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Technology Process of trans-bis{1,2-bis(dimethylphosphino)ethane}chloro(dinitrogen)iron(II) tetraphenylborate

There total 2 articles about trans-bis{1,2-bis(dimethylphosphino)ethane}chloro(dinitrogen)iron(II) tetraphenylborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: 27316-95-6,60966-88-3
trans-[FeCl₂(1,2-bis(dimethylphosphino)ethane)2]

: 143-66-8
sodium tetraphenyl borate

: 130172-25-7
trans-bis{1,2-bis(dimethylphosphino)ethane}chloro(dinitrogen)iron(II) tetraphenylborate

Guidance literature:: With N₂; In methanol; ethanol; addn. of trans-(FeCl2(dmpe)2) to ethanol under N2; dropwise addn. of a methanolic soln. of NaBPh4 to the stirred suspension; stirring under N2 for 1 h;; the ppt. was filtered off, washed with CH3OH and diethyl ether and dried under vac.; recrystn. from THF/ethanol under N2; elem. anal.;;
DOI:10.1039/DT9930000075

Reference yield: 72.0%

: 130172-27-9,130272-15-0
trans-bis{1,2-bis(dimethylphosphino)ethane}chloro(methylisocyanide)iron(II) tetraphenylborate

: 143-66-8
sodium tetraphenyl borate

: 130172-25-7
trans-bis{1,2-bis(dimethylphosphino)ethane}chloro(dinitrogen)iron(II) tetraphenylborate

Guidance literature:: With N₂; In methanol; dissolving of trans-(FeCl2(dmpe)2) in methanol under N2; dropwise addn. of a methanolic soln. of NaBPh4 to the stirred mixt.; stirring under N2 for 1 h;; the ppt. was filtered off, washed with CH3OH and diethyl ether and dried under vac.; recrystn. from THF/ethanol under N2; elem. anal.;;
DOI:10.1039/DT9930000075

Reference yield: 92.0%

: 593-75-9,685498-28-6
methyl isocyanate

: 130172-25-7
trans-bis{1,2-bis(dimethylphosphino)ethane}chloro(dinitrogen)iron(II) tetraphenylborate

: 130172-27-9,130272-15-0
trans-bis{1,2-bis(dimethylphosphino)ethane}chloro(methylisocyanide)iron(II) tetraphenylborate

Guidance literature:: In acetone; excess of CH3NC; performed under N2 or Ar;; recrystn. from acetone/hexane; elem. anal.;;
DOI:10.1039/DT9930000075