cis/trans-bis{1,2-bis(dimethylphosphino)ethane}carbonylchloroiron(II) tetraphenylborate

Base Information

Chemical Name:cis/trans-bis{1,2-bis(dimethylphosphino)ethane}carbonylchloroiron(II) tetraphenylborate
CAS No.:60876-39-3
Molecular Formula:C₁₃H₃₂ClFeOP₄*C₂₄H₂₀B
Molecular Weight:738.825
Hs Code.:

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Chemical Property of cis/trans-bis{1,2-bis(dimethylphosphino)ethane}carbonylchloroiron(II) tetraphenylborate

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Technology Process of cis/trans-bis{1,2-bis(dimethylphosphino)ethane}carbonylchloroiron(II) tetraphenylborate

There total 3 articles about cis/trans-bis{1,2-bis(dimethylphosphino)ethane}carbonylchloroiron(II) tetraphenylborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

: 130172-25-7
trans-bis{1,2-bis(dimethylphosphino)ethane}chloro(dinitrogen)iron(II) tetraphenylborate

: 60934-32-9,60876-39-3
cis/trans-bis{1,2-bis(dimethylphosphino)ethane}carbonylchloroiron(II) tetraphenylborate

Guidance literature:: With CO; In acetone; CO was bubbled through a soln. of trans-(FeCl(N2)(dmpe)2)(BPh4) in acetone; stirring for 10 min.; performed under N2 or Ar;; removal of solvent under vac.; the residue was dried and recrystd. from concd. CH2Cl2 soln. at -20°C; cis/trans (1:3) mixt. obtained; elem. anal.;;
DOI:10.1039/DT9930000075

Reference yield: 62.0%

: 27316-95-6,60966-88-3
trans-[FeCl₂(1,2-bis(dimethylphosphino)ethane)2]

: 143-66-8
sodium tetraphenyl borate

: 60876-39-3,60934-32-9
trans-bis[1,2-bis(dimethylphosphino)ethane]carbonylchloroiron(II) tetraphenylborate

: cis-bis[1,2-bis(dimethylphosphino)ethane]carbonylchloroiron(II) tetraphenylborate

Guidance literature:: With CO; In acetone; bubbling CO through refluxing soln. of Fe-complex for 5 h, cooling to room temp., slow addn. of NaBPh4 soln. (pre-satd. with CO); filtration, solvent removal (vac.), recrystn. (CH2Cl2), hand sepn. of isomers; elem. anal.;
DOI:10.1039/DT9760001232