Technology Process of 2,5-diboronoterephthalic acid
There total 5 articles about 2,5-diboronoterephthalic acid which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
hydrogenchloride; water;
at 40 ℃;
for 12h;
DOI:10.1039/c1jm14682c
- Guidance literature:
-
Multi-step reaction with 4 steps
1: potassium permanganate; water / tert-butyl alcohol
2: sulfuric acid / 5 h / Reflux
3: palladium bis[bis(diphenylphosphino)ferrocene] dichloride; potassium acetate / N,N-dimethyl-formamide / 20 h / 80 °C / Inert atmosphere
4: hydrogenchloride; water / 12 h / 40 °C
With
hydrogenchloride; potassium permanganate; palladium bis[bis(diphenylphosphino)ferrocene] dichloride; sulfuric acid; water; potassium acetate;
In
N,N-dimethyl-formamide; tert-butyl alcohol;
2: Fischer esterification;
DOI:10.1039/c1jm14682c
- Guidance literature:
-
Multi-step reaction with 5 steps
1: iodine; acetic acid; periodic acid
2: potassium permanganate; water / tert-butyl alcohol
3: sulfuric acid / 5 h / Reflux
4: bis-triphenylphosphine-palladium(II) chloride; triethylamine / toluene / 12 h / Reflux; Inert atmosphere
5: hydrogenchloride; water / 12 h / 40 °C
With
hydrogenchloride; bis-triphenylphosphine-palladium(II) chloride; potassium permanganate; sulfuric acid; water; iodine; acetic acid; periodic acid; triethylamine;
In
toluene; tert-butyl alcohol;
3: Fischer esterification;
DOI:10.1039/c1jm14682c
