tris[(triphenylphosphine)gold(I)]carbodiimide tetrafluoroborate

Base Information

• Chemical Name: tris[(triphenylphosphine)gold(I)]carbodiimide tetrafluoroborate
• CAS No.: 181264-76-6
• Molecular Formula: BF₄*C₅₅H₄₅Au₃N₂P₃
• Molecular Weight: 1504.6
• Mol file: 181264-76-6.mol

Synonyms:

Chemical Property of tris[(triphenylphosphine)gold(I)]carbodiimide tetrafluoroborate

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of tris[(triphenylphosphine)gold(I)]carbodiimide tetrafluoroborate

There total 1 articles about tris[(triphenylphosphine)gold(I)]carbodiimide tetrafluoroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

tris[triphenylphosphinegold(I)]oxonium tetrafluoroborate (53317-87-6) + bis(trimethylsilyl)carbodi-imide (1000-70-0) → tris[(triphenylphosphine)gold(I)]carbodiimide tetrafluoroborate (181264-76-6)

Guidance literature:

In tetrahydrofuran; dichloromethane; byproducts: O(SiMe3)2; (N2); -40 to 0°C over 2 h; solvent removal (vac.), addn. of CH2Cl2, pptn. with Et2O; elem. anal.;

DOI:10.1515/znb-1996-0607

Reference yield: 81.0%

(triphenylphosphine)gold(I) chloride (14243-64-2) + tris[(triphenylphosphine)gold(I)]carbodiimide tetrafluoroborate (181264-76-6) → tetrakis[(triphenylphosphine)gold(I)]carbodiimide tetrafluoroborate

Guidance literature:

With AgBF₄; In tetrahydrofuran; dichloromethane; byproducts: AgCl; (N2); addn. of AgBF4 to AuCl(PPh3) in THF at -40°C, filtration after 30 min, addn. of the Au complex in CH2Cl2, stirring (2 h), warming to 0°C; solvent removal (vac.), purifn. by pptn. from CH2Cl2/Et2O; elem. anal.;

DOI:10.1515/znb-1996-0607

upstream raw materials:

tris[triphenylphosphinegold(I)]oxonium tetrafluoroborate

bis(trimethylsilyl)carbodi-imide