[Mo₂Cp₂{μ-κ¹:η²-C(Ph)CO}(μ-PCy₂)(CO)(κ¹-N₂CPh₂)]

Base Information

• Chemical Name: [Mo₂Cp₂{μ-κ¹:η²-C(Ph)CO}(μ-PCy₂)(CO)(κ¹-N₂CPh₂)]
• CAS No.: 1313211-16-3
• Molecular Formula: C₄₄H₄₇Mo₂N₂O₂P
• Molecular Weight: 858.723
• Mol file: 1313211-16-3.mol

Synonyms:

Chemical Property of [Mo₂Cp₂{μ-κ¹:η²-C(Ph)CO}(μ-PCy₂)(CO)(κ¹-N₂CPh₂)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Mo₂Cp₂{μ-κ¹:η²-C(Ph)CO}(μ-PCy₂)(CO)(κ¹-N₂CPh₂)]

There total 5 articles about [Mo₂Cp₂{μ-κ¹:η²-C(Ph)CO}(μ-PCy₂)(CO)(κ¹-N₂CPh₂)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

carbon monoxide (201230-82-2) + [Mo2(η5-C5H5)2(μ-CPh)(μ-PCy2)(CO)2] (1286281-95-5) + diazodiphenylmethane (908093-98-1) → [Mo2Cp2{μ-κ1:η2-C(Ph)CO}(μ-PCy2)(CO)(κ1-N2CPh2)] (1313211-16-3)

Guidance literature:

[Mo2(η⁵-C₅H₅)₂(μ-CPh)(μ-PCy₂)(CO)₂]; diazodiphenylmethane; In diethyl ether; dichloromethane; at -196.16 - 20 ℃; for 0.0833333h; Inert atmosphere; Schlenk technique;

carbon monoxide; In dichloromethane; at 20 ℃; for 2h; Inert atmosphere; Schlenk technique;

DOI:10.1021/acs.organomet.6b00552

Reference yield: 89.0%

Mo2Cp2{(μ-C(Ph)CO)}(μ-PCy2)(CO)2 (1208114-70-8) + diazodiphenylmethane (908093-98-1) → [Mo2Cp2{μ-κ1:η2-C(Ph)CO}(μ-PCy2)(CO)(κ1-N2CPh2)] (1313211-16-3)

Guidance literature:

In diethyl ether; dichloromethane; at 20 ℃; for 0.0833333h; Inert atmosphere; Schlenk technique;

DOI:10.1021/acs.organomet.6b00552

Reference yield:

carbon monoxide (201230-82-2) + [Mo2(η5-C5H5)2(μ-CPh)(μ-PCy2)(CO)2] (1286281-95-5) + diazodiphenylmethane (908093-98-1) → [Mo2Cp2(μ-CPh)(μ-PCy2)(CO)(κ1-N2CPh2)] + [Mo2Cp2{μ-κ1:η2-C(Ph)CO}(μ-PCy2)(CO)(κ1-N2CPh2)] (1313211-16-3)

Guidance literature:

[Mo2(η⁵-C₅H₅)₂(μ-CPh)(μ-PCy₂)(CO)₂]; diazodiphenylmethane; In diethyl ether; dichloromethane; at 20 ℃; for 0.0833333h; Inert atmosphere; Schlenk technique;

carbon monoxide; In dichloromethane; at 20 ℃; for 2h; Inert atmosphere; Schlenk technique;

DOI:10.1021/acs.organomet.6b00552

upstream raw materials:

[Mo2(η⁵-C₅H₅)₂(μ-CPh)(μ-PCy₂)(CO)₂]

diazodiphenylmethane

carbon monoxide

Mo₂Cp₂{(μ-C(Ph)CO)}(μ-PCy₂)(CO)₂