[Ru(4'-tolyl-2,2':6',2''-terpyridine)(1,3-bis(1-butyl-1H-1,2,3-triazol-4-yl)benzene)]PF₆

Base Information

• Chemical Name: [Ru(4'-tolyl-2,2':6',2''-terpyridine)(1,3-bis(1-butyl-1H-1,2,3-triazol-4-yl)benzene)]PF₆
• CAS No.: 1285707-36-9
• Molecular Formula: C₄₀H₄₀N₉Ru*F₆P
• Molecular Weight: 892.852

Synonyms:

Chemical Property of [Ru(4'-tolyl-2,2':6',2''-terpyridine)(1,3-bis(1-butyl-1H-1,2,3-triazol-4-yl)benzene)]PF₆

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Technology Process of [Ru(4'-tolyl-2,2':6',2''-terpyridine)(1,3-bis(1-butyl-1H-1,2,3-triazol-4-yl)benzene)]PF₆

There total 1 articles about [Ru(4'-tolyl-2,2':6',2''-terpyridine)(1,3-bis(1-butyl-1H-1,2,3-triazol-4-yl)benzene)]PF₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 31.0%

potassium hexafluorophosphate (17084-13-8) + {Ru(4'-Ph-2,2':6',2''-terpyridine)Cl3} (146164-70-7) + 1,3-di(1-n-butyl-1,2,3-triazol-4-yl)benzene (1285707-21-2) + acetonitrile (75-05-8,26809-02-9) → [Ru(4'-tolyl-2,2':6',2''-terpyridine)(1,3-bis(1-butyl-1H-1,2,3-triazol-4-yl)benzene)]PF6 (1285707-36-9)

Guidance literature:

With silver triflate; In N,N-dimethyl-formamide; addn. of Ru(PhC5H2N(C5H4N)2)Cl3 and AgOTf to Me2CO, reflux for 3 h, cooling to room temp., filtration, concn. to dryness, addn. of C6H4(C2HN3Bu)2, DMF, reflux for 24 h, cooling to room temp., removal of solvent, dissolving in MeOH, addn. of excess KPF6; pptn., filtration, washing with H2O and Et2O, chromy. on silica gel (eluent: CH2Cl2/CH3CN, 10:1); elem. anal.;

DOI:10.1021/om200039j

Reference yield: 80.0%

[Ru(4'-tolyl-2,2':6',2''-terpyridine)(1,3-bis(1-butyl-1H-1,2,3-triazol-4-yl)benzene)]PF6 (1285707-36-9) + water (7732-18-5) → [(4'-tolyl-2,2':6',2''-terpyridine)2Ru2(μ-3,3',5,5'-tetrakis(1-butyl-1H-1,2,3-triazol-4-yl)biphenyl)](PF6)2*5H2O

Guidance literature:

With AgBF₄; KPF₆; In butan-1-ol; a mixt. of Ru-complex and AgBF4 in n-butanol was refluxed for 5 h, the solvent was removed, aq. KPF6 was added to CH2Cl2-soln.; ppt. was filtered, washed with water and diethyl ether, flash chromy. (eluent CH3CN/aq. KNO3/H2O 200/1/5) on silica gel followed by anion exchange with KPF6; elem. anal.;

DOI:10.1021/om201112h

upstream raw materials:

potassium hexafluorophosphate

{Ru(4'-Ph-2,2':6',2''-terpyridine)Cl3}

1,3-di(1-n-butyl-1,2,3-triazol-4-yl)benzene

acetonitrile

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