Ru^III(pyridine-2,6-dicarboxylate)(PPh₃)₂(Cl)

Base Information

• Chemical Name: Ru^III(pyridine-2,6-dicarboxylate)(PPh₃)₂(Cl)
• CAS No.: 1310057-66-9
• Molecular Formula: C₄₃H₃₃ClNO₄P₂Ru
• Molecular Weight: 826.21
• Mol file: 1310057-66-9.mol

Synonyms:

Chemical Property of Ru^III(pyridine-2,6-dicarboxylate)(PPh₃)₂(Cl)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of Ru^III(pyridine-2,6-dicarboxylate)(PPh₃)₂(Cl)

There total 3 articles about Ru^III(pyridine-2,6-dicarboxylate)(PPh₃)₂(Cl) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

Pyridine-2,6-dicarboxylic acid (499-83-2) + [tris(triphenylphosphine) ruthenium(III) trichloride] (30050-39-6,23311-38-8) → trans-[ruthenium(III) (2,6-pyridine dicarboxylate(2-)) (triphenylphosphine)2 (chloride)] (1310057-66-9,907996-79-6)

Guidance literature:

In ethanol; benzene; benzene soln. of RuCl3(PPh3)3 added to a refluxing soln. of dipicolinic acid in ethanol; mixture heated under reflux for 6 h; filtered while hot; reduced to half volume; left for slow evaporation; crystalline product filtered off; washed with ethanol; dried under vacuum; recrystallized from benzene/ethanol mixture; elem. anal.;

DOI:10.1016/j.poly.2006.01.023

Reference yield: 70.0%

cis,mer-[Ru(2,6-pyridinedicarboxylate)(PPh3)2Cl]*2H2O → trans-[ruthenium(III) (2,6-pyridine dicarboxylate(2-)) (triphenylphosphine)2 (chloride)] (1310057-66-9,907996-79-6)

Guidance literature:

In chloroform; (under N2); Ru-complex added slowly to soln. of CHCl3, refluxed for 7 h; filtered, rotary evapd.; elem. anal.;

DOI:10.1016/j.molstruc.2011.02.044

Reference yield: 62.0%

tris(triphenylphosphine)ruthenium(II) chloride (15529-49-4,41756-81-4) + Pyridine-2,6-dicarboxylic acid (499-83-2) → RuIII(pyridine-2,6-dicarboxylate)(PPh3)2(Cl) (907996-79-6,1310057-66-9)

Guidance literature:

In ethanol;

DOI:10.1002/ejic.201301225

upstream raw materials:

Pyridine-2,6-dicarboxylic acid

[tris(triphenylphosphine) ruthenium(III) trichloride]

tris(triphenylphosphine)ruthenium(II) chloride