((C₆H₅)3P)AuCCCH₂CH₂OC₅H₉O

Base Information

• Chemical Name: ((C₆H₅)3P)AuCCCH₂CH₂OC₅H₉O
• CAS No.: 1349835-52-4
• Molecular Formula: C₂₇H₂₈AuO₂P
• Molecular Weight: 612.458
• Mol file: 1349835-52-4.mol

Synonyms:

Chemical Property of ((C₆H₅)3P)AuCCCH₂CH₂OC₅H₉O

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of ((C₆H₅)3P)AuCCCH₂CH₂OC₅H₉O

There total 1 articles about ((C₆H₅)3P)AuCCCH₂CH₂OC₅H₉O which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.8%

2-(but-3-yn-1-yloxy)tetrahydropyran (40365-61-5) + (triphenylphosphine)gold(I) chloride (14243-64-2) → ((C6H5)3P)AuCCCH2CH2OC5H9O (1349835-52-4)

Guidance literature:

With sodium hydroxide; In methanol; dichloromethane; (N2) react. Au complex, alkyne and NaOH in CH2Cl2-MeOH was stirred overnight; volatiles were removed in vacuo, residue was extd. with benzene and filtered, recrystn. by pentane diffusion; elem. anal.;

DOI:10.1039/c1dt11337b

Reference yield: 83.0%

((C6H5)3P)AuCCCH2CH2OC5H9O (1349835-52-4) + phosphonic acid diethyl ester (762-04-9) → Ph3PAu(P(O)(OEt)2)

Guidance literature:

In benzene-d6; 64°C; soln. was concd. in vacuo, triturated with Et2O-hexane (2:1) and dried in vacuo; elem. anal.;

DOI:10.1039/c1dt11337b

upstream raw materials:

2-(but-3-yn-1-yloxy)tetrahydropyran

(triphenylphosphine)gold(I) chloride