Re(CO)3(OC₆H₄NO₂)(C₆H₄(As(CH₃)2)2)

Base Information

Chemical Name:Re(CO)3(OC₆H₄NO₂)(C₆H₄(As(CH₃)2)2)
CAS No.:144812-18-0
Molecular Formula:C₁₉H₂₀As₂NO₆Re
Molecular Weight:694.421
Hs Code.:

Re(CO)3(OC<sub>6</sub>H<sub>4</sub>NO<sub>2</sub>)(C<sub>6</sub>H<sub>4</sub>(As(CH<sub>3</sub>)2)2)

Synonyms:

Suppliers and Price of Re(CO)3(OC₆H₄NO₂)(C₆H₄(As(CH₃)2)2)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemicals and raw materials
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price

Total 2 raw suppliers

Chemical Property of Re(CO)3(OC₆H₄NO₂)(C₆H₄(As(CH₃)2)2)

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

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Technology Process of Re(CO)3(OC₆H₄NO₂)(C₆H₄(As(CH₃)2)2)

There total 3 articles about Re(CO)3(OC₆H₄NO₂)(C₆H₄(As(CH₃)2)2) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 100-02-7,78813-13-5,89830-32-0
4-nitro-phenol

: 138695-29-1
(CO)3(C₆H₄(As(CH₃)2)2)ReOCH₃

: 144812-18-0
Re(CO)3(OC₆H₄NO₂)(C₆H₄(As(CH₃)2)2)

Guidance literature:: In benzene; charging a bomb with Re-compound, HOC6H4NO2 and C6H6; heating at 44°C for 10 h; inert atm.;; removal of solvent under vac., removal of excess HOC6H4NO2 by sublimation at 45°C; crystallization by layering a CH2Cl2 soln. with hexane for 2 days at room temperature; filtration; washing with pentane; drying in high vac.;;
DOI:10.1021/om00027a031

Reference yield:

: 144812-17-9
Re(CO)3(OC₆H₄CH₃)(C₆H₄(As(CH₃)2)2)

: 830-03-5
4-nitrophenol acetate

: 144812-18-0
Re(CO)3(OC₆H₄NO₂)(C₆H₄(As(CH₃)2)2)

Guidance literature:: In chloroform-d1; NMR tube charged with complex and solvent in a drybox, addn. of soln. of organic compd. via pipet, kept at room temp. for 24 h; not isolated; 1H-NMR;

Reference yield:

: 138695-29-1
(CO)3(C₆H₄(As(CH₃)2)2)ReOCH₃

: 830-03-5
4-nitrophenol acetate

: 144812-18-0
Re(CO)3(OC₆H₄NO₂)(C₆H₄(As(CH₃)2)2)

Guidance literature:: In benzene-d6; byproducts: methyl acetate; NMR tube charged with complex and solvent in a drybox, addn. of tolyl acetate via syringe, kept at room temp. for 12 h; not isolated; 1H-NMR;