Imidazole-1-carbothioic acid O-{(2R,3S)-1-benzo[1,3]dioxol-5-yl-3-[(4S,5S)-5-(benzyloxyimino-methyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-2,3-bis-methoxymethoxy-propyl} ester

Base Information

Chemical Name:Imidazole-1-carbothioic acid O-{(2R,3S)-1-benzo[1,3]dioxol-5-yl-3-[(4S,5S)-5-(benzyloxyimino-methyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-2,3-bis-methoxymethoxy-propyl} ester
CAS No.:236387-88-5
Molecular Formula:C₃₁H₃₇N₃O₁₀S
Molecular Weight:643.715
Hs Code.:

Imidazole-1-carbothioic acid O-{(2R,3S)-1-benzo[1,3]dioxol-5-yl-3-[(4S,5S)-5-(benzyloxyimino-methyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-2,3-bis-methoxymethoxy-propyl} ester

Synonyms:

Suppliers and Price of Imidazole-1-carbothioic acid O-{(2R,3S)-1-benzo[1,3]dioxol-5-yl-3-[(4S,5S)-5-(benzyloxyimino-methyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-2,3-bis-methoxymethoxy-propyl} ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Imidazole-1-carbothioic acid O-{(2R,3S)-1-benzo[1,3]dioxol-5-yl-3-[(4S,5S)-5-(benzyloxyimino-methyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-2,3-bis-methoxymethoxy-propyl} ester

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Imidazole-1-carbothioic acid O-{(2R,3S)-1-benzo[1,3]dioxol-5-yl-3-[(4S,5S)-5-(benzyloxyimino-methyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-2,3-bis-methoxymethoxy-propyl} ester

There total 4 articles about Imidazole-1-carbothioic acid O-{(2R,3S)-1-benzo[1,3]dioxol-5-yl-3-[(4S,5S)-5-(benzyloxyimino-methyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-2,3-bis-methoxymethoxy-propyl} ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 17680-04-5
(3,4-methylenedioxy)phenylmagnesium bromide

: 236387-88-5
Imidazole-1-carbothioic acid O-{(2R,3S)-1-benzo[1,3]dioxol-5-yl-3-[(4S,5S)-5-(benzyloxyimino-methyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-2,3-bis-methoxymethoxy-propyl} ester

Guidance literature:: Multi-step reaction with 2 steps

1: 82 percent / tetrahydrofuran / 3.5 h / -78 - -10 °C

2: DMAP / 1,2-dichloro-ethane / 24 h / Heating

With dmap; In tetrahydrofuran; 1,2-dichloro-ethane;
DOI:10.1021/jo9902042

Reference yield:

: (4S,5S)-5-((1R,2S)-1,2-Bis-methoxymethoxy-3-oxo-propyl)-2,2-dimethyl-[1,3]dioxolane-4-carbaldehyde O-benzyl-oxime

: 236387-88-5
Imidazole-1-carbothioic acid O-{(2R,3S)-1-benzo[1,3]dioxol-5-yl-3-[(4S,5S)-5-(benzyloxyimino-methyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-2,3-bis-methoxymethoxy-propyl} ester

Guidance literature:: Multi-step reaction with 2 steps

1: 82 percent / tetrahydrofuran / 3.5 h / -78 - -10 °C

2: DMAP / 1,2-dichloro-ethane / 24 h / Heating

With dmap; In tetrahydrofuran; 1,2-dichloro-ethane;
DOI:10.1021/jo9902042

Reference yield:

: (3S,2R)-3-<(5S,4R)-5-<(1Z/E)-2-aza-2-(phenylmethoxy)vinyl>-2,2-dimethyl(1,3-dioxolan-4-yl)>-2,3-bis(methoxymethyl)propan-1-ol

: 236387-88-5
Imidazole-1-carbothioic acid O-{(2R,3S)-1-benzo[1,3]dioxol-5-yl-3-[(4S,5S)-5-(benzyloxyimino-methyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-2,3-bis-methoxymethoxy-propyl} ester

Guidance literature:: Multi-step reaction with 3 steps

1: 87 percent / NMO, tetrapropylammonium perruthenate / CH₂Cl₂ / 0.5 h / Ambient temperature

2: 82 percent / tetrahydrofuran / 3.5 h / -78 - -10 °C

3: DMAP / 1,2-dichloro-ethane / 24 h / Heating

With dmap; N-methyl-2-indolinone; tetrapropylammonium perruthennate; In tetrahydrofuran; dichloromethane; 1,2-dichloro-ethane;
DOI:10.1021/jo9902042