Pt(acetylacetonate)(4,6-di-(4-tert-butylphenyl)pyrimidine)

Base Information

• Chemical Name: Pt(acetylacetonate)(4,6-di-(4-tert-butylphenyl)pyrimidine)
• CAS No.: 1309879-71-7
• Molecular Formula: C₂₉H₃₄N₂O₂Pt
• Molecular Weight: 637.681
• Mol file: 1309879-71-7.mol

Synonyms:

Chemical Property of Pt(acetylacetonate)(4,6-di-(4-tert-butylphenyl)pyrimidine)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of Pt(acetylacetonate)(4,6-di-(4-tert-butylphenyl)pyrimidine)

There total 1 articles about Pt(acetylacetonate)(4,6-di-(4-tert-butylphenyl)pyrimidine) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 52.0%

potassium tetrachloroplatinate(II) (10025-99-7) + tetrakis(triphenylphosphine) palladium(0) (14221-01-3) + sodium (Z)-4-oxopent-2-en-2-olate (1118-67-8) → Pt(acetylacetonate)(4,6-di-(4-tert-butylphenyl)pyrimidine) (1309879-71-7)

Guidance literature:

In water; acetic acid; dimethyl sulfoxide; mixt. of ligand, K2PtCl4 in acetic acid refluxed for 14 h, solvent removed by rotary evaporator, residue dissolved in DMSO, refluxed for 1 min, cooled to room temp., H2O added, filtered, washed with H2O, dissolved inacetone, Na-salt added, refluxed 5 h; H2O added, filtered, washed with H2O, column chromy. on silica gel with CH2Cl2; elem. anal.;

DOI:10.1021/ic200706e

upstream raw materials:

potassium tetrachloroplatinate(II)

tetrakis(triphenylphosphine) palladium⁽⁰⁾

sodium (Z)-4-oxopent-2-en-2-olate