ReH₂(P(C₆H₅)3)3(NCCH₃)2⁽¹⁺⁾*PF₆^(1-)={ReH₂(P(C₆H₅)3)3(NCCH₃)2}PF₆

Base Information

• Chemical Name: ReH₂(P(C₆H₅)3)3(NCCH₃)2⁽¹⁺⁾*PF₆^(1-)={ReH₂(P(C₆H₅)3)3(NCCH₃)2}PF₆
• CAS No.: 108530-75-2
• Molecular Formula: C₅₈H₅₃N₂P₃Re*F₆P
• Molecular Weight: 1202.16
• Mol file: 108530-75-2.mol

Synonyms:

Chemical Property of ReH₂(P(C₆H₅)3)3(NCCH₃)2⁽¹⁺⁾*PF₆^(1-)={ReH₂(P(C₆H₅)3)3(NCCH₃)2}PF₆

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of ReH₂(P(C₆H₅)3)3(NCCH₃)2⁽¹⁺⁾*PF₆^(1-)={ReH₂(P(C₆H₅)3)3(NCCH₃)2}PF₆

There total 1 articles about ReH₂(P(C₆H₅)3)3(NCCH₃)2⁽¹⁺⁾*PF₆^(1-)={ReH₂(P(C₆H₅)3)3(NCCH₃)2}PF₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

ReH3(P(C6H5)3)3(NCCH3) (108530-77-4) + tropylium hexafluorophosphate (29663-54-5) + acetonitrile (75-05-8,26809-02-9) → ReH(P(C6H5)3)3(NCCH3)3(2+)*2(PF6)(1-)={ReH(P(C6H5)3)3(NCCH3)3}(PF6)2 + ReH2(P(C6H5)3)3(NCCH3)2(1+)*PF6(1-)={ReH2(P(C6H5)3)3(NCCH3)2}PF6 (108530-75-2)

Guidance literature:

In diethyl ether; A mixt. of reagents was added to a Et2O contained a small quantity of CH3CN, the mixt. was stirred for 45 min (N2 atm.);; ppt. was filtered off, washed with Et2O; elem. anal.;;

DOI:10.1039/DT9870000715

Reference yield: 58.0%

ReH2(P(C6H5)3)3(NCCH3)2(1+)*PF6(1-)={ReH2(P(C6H5)3)3(NCCH3)2}PF6 (108530-75-2) + tropylium hexafluorophosphate (29663-54-5) + acetonitrile (75-05-8,26809-02-9) → ReH(P(C6H5)3)3(NCCH3)3(2+)*2(PF6)(1-)={ReH(P(C6H5)3)3(NCCH3)3}(PF6)2

Guidance literature:

In acetonitrile; CH3CN, 30 min, N2 atm.;; Et2O was added, ppt. was filtered off;;

DOI:10.1039/DT9870000715

upstream raw materials:

ReH₃(P(C₆H₅)3)3(NCCH₃)

tropylium hexafluorophosphate

acetonitrile