RuCl(C₁₄H₂₁C₁₅H₁₀N₃)(N₂C₃₆H₃₈O₈(C₆H₄CN)(C₂H₄SOCH₃))⁽¹⁺⁾*PF₆^(1-)=[RuCl(C₂₉H₃₁N₃)(N₂C₃₆H₃₈O₈(C₆H₄CN)(C₂H₄SOCH₃))]PF₆

Base Information

• Chemical Name: RuCl(C₁₄H₂₁C₁₅H₁₀N₃)(N₂C₃₆H₃₈O₈(C₆H₄CN)(C₂H₄SOCH₃))⁽¹⁺⁾*PF₆^(1-)=[RuCl(C₂₉H₃₁N₃)(N₂C₃₆H₃₈O₈(C₆H₄CN)(C₂H₄SOCH₃))]PF₆
• CAS No.: 888940-16-7
• Molecular Formula: C₇₅H₈₀ClN₆O₉RuS*F₆P
• Molecular Weight: 1523.05
• Mol file: 888940-16-7.mol

Synonyms:

Chemical Property of RuCl(C₁₄H₂₁C₁₅H₁₀N₃)(N₂C₃₆H₃₈O₈(C₆H₄CN)(C₂H₄SOCH₃))⁽¹⁺⁾*PF₆^(1-)=[RuCl(C₂₉H₃₁N₃)(N₂C₃₆H₃₈O₈(C₆H₄CN)(C₂H₄SOCH₃))]PF₆

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of RuCl(C₁₄H₂₁C₁₅H₁₀N₃)(N₂C₃₆H₃₈O₈(C₆H₄CN)(C₂H₄SOCH₃))⁽¹⁺⁾*PF₆^(1-)=[RuCl(C₂₉H₃₁N₃)(N₂C₃₆H₃₈O₈(C₆H₄CN)(C₂H₄SOCH₃))]PF₆

There total 3 articles about RuCl(C₁₄H₂₁C₁₅H₁₀N₃)(N₂C₃₆H₃₈O₈(C₆H₄CN)(C₂H₄SOCH₃))⁽¹⁺⁾*PF₆^(1-)=[RuCl(C₂₉H₃₁N₃)(N₂C₃₆H₃₈O₈(C₆H₄CN)(C₂H₄SOCH₃))]PF₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

Ru(C14H21C15H10N3)(N2C36H38O8(C6H4CN)(C2H4SOCH3))(2+)*2PF6(1-)=[Ru(C29H31N3)(N2C36H38O8(C6H4CN)(C2H4SOCH3))](PF6)2 + tetraethylammonium chloride (56-34-8) → RuCl(C14H21C15H10N3)(N2C36H38O8(C6H4CN)(C2H4SOCH3))(1+)*PF6(1-)=[RuCl(C29H31N3)(N2C36H38O8(C6H4CN)(C2H4SOCH3))]PF6 (888940-16-7,889103-60-0)

Guidance literature:

With potassium hexafluorophosphate; In dichloromethane-d2; Irradiation (UV/VIS); soln. of Ru complex and Et4NCl in CD2Cl2 irradiated (xenon 1000 W lamp fitted with water filter and Andover 470FS10-50 interference filter) at 25°C for 2 h, aq. KPF6 added; ppt. filtered off, washed with water, recovered with acetone and dried under vac.;

DOI:10.1021/ic060029p

Reference yield:

Ru(C14H21C15H10N3)(N2C36H38O8(C6H4CN)(C2H4SOCH3))(2+)*2PF6(1-)=[Ru(C29H31N3)(N2C36H38O8(C6H4CN)(C2H4SOCH3))](PF6)2 + tetraethylammonium chloride (56-34-8) → RuCl(C14H21C15H10N3)(N2C36H38O8(C6H4CN)(C2H4SOCH3))(1+)*PF6(1-)=[RuCl(C29H31N3)(N2C36H38O8(C6H4CN)(C2H4SOCH3))]PF6 (888940-16-7,889103-60-0)

Guidance literature:

With potassium hexafluorophosphate; In dichloromethane-d2; Irradiation (UV/VIS); soln. of Ru complex and Et4NCl in CD2Cl2 irradiated (xenon 1000 W lamp fitted with water filter and Andover 470FS10-50 interference filter) at 25°C for 2 h, aq. KPF6 added; ppt. filtered off, washed with water, recovered with acetone and dried under vac.;

DOI:10.1021/ic060029p

Reference yield:

potassium hexafluorophosphate (17084-13-8) + Ru(4'-(3,5-bis(tert-butyl)phenyl)-2,2':6',2''-terpyridine)Cl3 (660860-77-5) + N2C12H6(C6H4O(CH2CH2O)3C6H4CN)(C6H4O(CH2CH2O)3CH2CH2SOCH3) (888940-08-7) → (RuCl(C14H21C15H10N3)(N2C36H38O8(C6H4CN)(C2H4SOCH3)))(1+)*PF6(1-)=[RuCl(C29H31N3)(N2C36H38O8(C6H4CN)(C2H4SOCH3))]PF6 (888940-16-7,889103-60-0)

Guidance literature:

With lithium chloride; In ethanol; water; under Ar; hot soln. of phenanthroline derivative in EtOH added to suspn.Ru complex and LiCl in aq. EtOH, mixt. heated at reflux for 5 h, aq. KP F6 added to cooled soln.; EtOH evapd. under vac., ppt. filtered off, washed with water, solid recovered with acetone and evapd. to dryness, chromy. (silica, acetone/water/satd. KNO3 (300/15/2); isomers not separated;

DOI:10.1021/ic060029p

upstream raw materials:

potassium hexafluorophosphate

Ru(4'-(3,5-bis(tert-butyl)phenyl)-2,2':6',2''-terpyridine)Cl₃

N₂C₁₂H₆(C₆H₄O(CH₂CH₂O)3C₆H₄CN)(C₆H₄O(CH₂CH₂O)3CH₂CH₂SOCH₃)

tetraethylammonium chloride