[(Z)-1-Chloro-2-phenylethenyl]benzene

Base Information

• Chemical Name: [(Z)-1-Chloro-2-phenylethenyl]benzene
• CAS No.: 948-99-2
• Molecular Formula: C14H11 Cl
• Molecular Weight: 214.694
• NSC Number: 168887
• DSSTox Substance ID: DTXSID101034467
• Nikkaji Number: J120.863B,J590.484F
• Mol file: 948-99-2.mol

Synonyms:[(Z)-1-Chloro-2-phenylethenyl]benzene;1460-06-6;1,2-Diphenyl-1-chloroethene;1-CHLORO-1,2-DIPHENYLETHENE;948-99-2;Stilbene, .alpha.-chloro-, (E)-;alpha-Chlorostilbene;NSC168887;(Z)-alpha-Chlorostilbene;Benzene, 1,1'-(1-chloro-1,2-ethenediyl)bis-, (E)-;Stilbene, .alpha.-chloro-;trans-.alpha.-Chlorostilbene;SCHEMBL6065187;SCHEMBL6065195;VVFIZEWCXRQNGK-KAMYIIQDSA-N;DTXSID101034467;948-98-1;NSC-168887;[(E)-1-Chloro-2-phenylethenyl]benzene;[(Z)-1-chloro-2-phenyl-vinyl]-benzene;1,1'-[(Z)-1-Chloro-1,2-ethenediyl]dibenzene;Benzene, 1,1'-(1-chloro-1,2-ethenediyl)bis-

Chemical Property of [(Z)-1-Chloro-2-phenylethenyl]benzene

Chemical Property:

• XLogP3: 4.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 2
• Exact Mass: 214.0549280
• Heavy Atom Count: 15
• Complexity: 207

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C=C(C2=CC=CC=C2)Cl
• Isomeric SMILES: C1=CC=C(C=C1)/C=C(/C2=CC=CC=C2)\Cl

Technology Process of [(Z)-1-Chloro-2-phenylethenyl]benzene

There total 33 articles about [(Z)-1-Chloro-2-phenylethenyl]benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

(2,2-dichlorovinyl)benzene (698-88-4) + phenylmagnesium bromide → α-chloro-(Z)-stilbene (948-99-2)

Guidance literature:

With PdCl₂(dbbp); In diethyl ether; for 22h; Heating;

DOI:10.1021/ja00238a052

Reference yield: 98.0%

meso-1,2-dichloro-1,2-diphenylethane (15951-99-2) → α-chloro-(Z)-stilbene (948-99-2)

Guidance literature:

With sodium sulfide; Aliquat 336; In water; benzene; for 6h; Heating;

DOI:10.1016/S0040-4039(00)88080-6

Reference yield: 97.0%

C20H17Cl3Se (109391-86-8) → α-chloro-(Z)-stilbene (948-99-2)

Guidance literature:

With sodium hydrogencarbonate; In dichloromethane; for 24h;

DOI:10.1021/jo00227a026

upstream raw materials:

phenyl benzyl ketone

meso-1,2-dichloro-1,2-diphenylethane

(2,2-dichlorovinyl)benzene

phenylzinc(II) bromide

Downstream raw materials:

(E)-1,2-diphenyl-ethene

(E)-α-chlorostilbene

diphenyl acetylene

benzoic acid methyl ester