N-phenyl-benzenesulfanylketenimine

Base Information

• Chemical Name: N-phenyl-benzenesulfanylketenimine
• CAS No.: 227096-83-5
• Molecular Formula: C₁₄H₁₁NS
• Molecular Weight: 225.314
• Mol file: 227096-83-5.mol

Synonyms:

Chemical Property of N-phenyl-benzenesulfanylketenimine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N-phenyl-benzenesulfanylketenimine

There total 2 articles about N-phenyl-benzenesulfanylketenimine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

S-methyl α-(trimethylsilyl)ethanimidothioate (134948-24-6) → N-phenyl-benzenesulfanylketenimine (227096-83-5)

Guidance literature:

Multi-step reaction with 2 steps

1: 1.) n-BuLi, 2.) propylene oxide / 1) THF, hexane, -78 deg C, 1 h; 2) THF, hexane, rt, 1 h

2: 2.) aq. NH₄Cl, aq. HCl, 3.) Et₃N / 1) CH₂Cl₂, 0 deg C, 5 min; 2) CH₂Cl₂, rt, 1 h

With hydrogenchloride; n-butyllithium; ammonium chloride; triethylamine; methyloxirane;

DOI:10.1016/S0040-4020(99)00219-7

Reference yield:

N-phenyl-(trimethylsilyl)ketenimine (134916-85-1) + benzenesulfenyl chloride (931-59-9) → N-phenyl-benzenesulfanylketenimine (227096-83-5)

Guidance literature:

With hydrogenchloride; ammonium chloride; triethylamine; Yield given; Multistep reaction; 1) CH₂Cl₂, 0 deg C, 5 min; 2) CH₂Cl₂, rt, 1 h;

DOI:10.1016/S0040-4020(99)00219-7

Reference yield:

N-phenyl-benzenesulfanylketenimine (227096-83-5) → N-phenyl-2-benzenesulfanylacetamide (4686-01-5)

Guidance literature:

With water; In acetone; Yield given;

DOI:10.1016/S0040-4020(99)00219-7

upstream raw materials:

N-phenyl-(trimethylsilyl)ketenimine

benzenesulfenyl chloride

S-methyl α-(trimethylsilyl)ethanimidothioate

Downstream raw materials:

N-phenyl-2-benzenesulfanylacetamide