tricarbonyl(η5-2-thienylphenylmethanol)chromium(0)

Base Information

• Chemical Name: tricarbonyl(η5-2-thienylphenylmethanol)chromium(0)
• CAS No.: 154789-10-3
• Molecular Formula: C₁₄H₁₀CrO₄S
• Molecular Weight: 326.293
• Mol file: 154789-10-3.mol

Synonyms:

Chemical Property of tricarbonyl(η5-2-thienylphenylmethanol)chromium(0)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tricarbonyl(η5-2-thienylphenylmethanol)chromium(0)

There total 1 articles about tricarbonyl(η5-2-thienylphenylmethanol)chromium(0) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 39.0%

thiophene-chromiumtricarbonyl (1092684-31-5,12078-15-8,1046161-58-3) + benzaldehyde (100-52-7) → tricarbonyl(η5-2-thienylphenylmethanol)chromium(0) (154902-95-1,155604-82-3,154789-10-3)

Guidance literature:

With n-butyllithium; In tetrahydrofuran; hexane; byproducts: 2-thienylphenylmethanol; (Ar); at -78°C, soln. of BuLi in hexane added to soln. of Cr complex in THF; mixt. stirred for 30 min; aldehyde added; mixt. stirred for 30 min; warmed to 0°C; added to ice water contg. HCl; extn. with benzene; ext. dried over Na2SO4; evapd. in vac.; chromy. (SiO2, benzene); diastereoisomers sepd.; evapn. in vac.; crystn. from benzene/light petroleum; ratio of diastereoisomers 72:28; elem. anal.;

DOI:10.1016/0022-328X(94)87009-8

upstream raw materials:

thiophene-chromiumtricarbonyl

benzaldehyde