C₅₉H₇₉NO₁₃SSi₂

Base Information

• Chemical Name: C₅₉H₇₉NO₁₃SSi₂
• CAS No.: 943321-06-0
• Molecular Formula: C₅₉H₇₉NO₁₃SSi₂
• Molecular Weight: 1098.51
• Mol file: 943321-06-0.mol

Synonyms:

Chemical Property of C₅₉H₇₉NO₁₃SSi₂

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₅₉H₇₉NO₁₃SSi₂

There total 2 articles about C₅₉H₇₉NO₁₃SSi₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C37H52O10SSi (943321-04-8) + (3R,4S)-1-benzoyl-4-phenyl-3-(triethylsilyl)oxy-2-azetidinone (149249-91-2) → C59H79NO13SSi2 (943321-06-0)

Guidance literature:

C₃₇H₅₂O₁₀SSi; With lithium hexamethyldisilazane; In tetrahydrofuran; at -50 ℃; for 0.666667h;

(3R,4S)-1-benzoyl-4-phenyl-3-(triethylsilyl)oxy-2-azetidinone; In tetrahydrofuran; at -40 ℃; for 0.5h; Further stages.;

DOI:10.1016/j.bmcl.2007.03.026

Reference yield:

C37H50O10SSi → C59H79NO13SSi2 (943321-06-0)

Guidance literature:

Multi-step reaction with 2 steps

1.1: 80 percent / sodium borohydride / tetrahydrofuran; methanol / 18 h / 20 °C

2.1: lithium bis(trimethylsilyl)amide / tetrahydrofuran / 0.67 h / -50 °C

2.2: tetrahydrofuran / 0.5 h / -40 °C

With sodium tetrahydroborate; lithium hexamethyldisilazane; In tetrahydrofuran; methanol;

DOI:10.1016/j.bmcl.2007.03.026

Reference yield:

C59H79NO13SSi2 (943321-06-0) → C47H51NO13S

Guidance literature:

With pyridine; hydrogen fluoride; In acetonitrile; at 20 ℃; for 8h;

DOI:10.1016/j.bmcl.2007.03.026

upstream raw materials:

C₃₇H₅₂O₁₀SSi

(3R,4S)-1-benzoyl-4-phenyl-3-(triethylsilyl)oxy-2-azetidinone