dicarbonylbis(triphenylphosphane)ruthenium(II) difluoride

Base Information

Chemical Name:dicarbonylbis(triphenylphosphane)ruthenium(II) difluoride
CAS No.:165555-49-7
Molecular Formula:C₃₈H₃₀F₂O₂P₂Ru
Molecular Weight:719.669
Hs Code.:

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Chemical Property of dicarbonylbis(triphenylphosphane)ruthenium(II) difluoride

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Technology Process of dicarbonylbis(triphenylphosphane)ruthenium(II) difluoride

There total 2 articles about dicarbonylbis(triphenylphosphane)ruthenium(II) difluoride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: (tricarbonyl)ruthenium difluoride tetramer

: 603-35-0
triphenylphosphine

: 165555-49-7
dicarbonylbis(triphenylphosphane)ruthenium(II) difluoride

Guidance literature:: In acetone; byproducts: CO; (N2); stirring (3 h); removal of solvent (vac.), recrystn. (benzene/light petroleum); elem. anal.;
DOI:10.1039/a702142i

Reference yield:

: xenon fluoride

: 20332-49-4,14741-36-7
tricarbonylbis(triphenylphosphine)ruthenium⁽⁰⁾

: 165555-49-7
dicarbonylbis(triphenylphosphane)ruthenium(II) difluoride

Guidance literature:: In dichloromethane-d2; metal vac. line, pre-fluorinated reactors; condensing CD2Cl2 on mixt. of Ru-complex and excess XeF2 (-196°C), warming to 220 K, then refluxing (several h); solvent removal (low temp.);
DOI:10.1039/DT9950001073

Reference yield: 95.0%

: 165555-49-7
dicarbonylbis(triphenylphosphane)ruthenium(II) difluoride

: 109-63-7
trifluoroborane diethyl ether

: 75-05-8,26809-02-9
acetonitrile

: 1254985-78-8
[ruthenium(II)(acetonitrile)2(dicarbonyl)bis(triphenylphosphane)] tetrafluoroborate heptafluorodiborate

Guidance literature:: In acetonitrile; Schlenk technique, in dry box, under N2; BF3*OEt2 (excess) added dropwise to soln. of Ru complex (0.347 mmol) in acetonitrile at stirring at room temp., stirred for 10 h; volatiles removed under vac., crystd. from CH2Cl2/Et2O (1:100), from CH2Cl2/hexane (1:100); elem. anal.;
DOI:10.1002/ejic.201000410