[IrCl(C6H4-2-C(H)=NPh-κC,N)(η-C5Me5)]

Base Information

Chemical Name:[IrCl(C6H4-2-C(H)=NPh-κC,N)(η-C5Me5)]
CAS No.:674800-05-6
Molecular Formula:C₂₃H₂₅ClIrN
Molecular Weight:543.131
Hs Code.:

Synonyms:

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Chemical Property of [IrCl(C6H4-2-C(H)=NPh-κC,N)(η-C5Me5)]

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Technology Process of [IrCl(C6H4-2-C(H)=NPh-κC,N)(η-C5Me5)]

There total 2 articles about [IrCl(C6H4-2-C(H)=NPh-κC,N)(η-C5Me5)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 12354-84-6,12354-85-7
bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]

: 538-51-2
benzylidene phenylamine

: 674800-05-6
[IrCl(C6H4-2-C(H)=NPh-κC,N)(η-C5Me5)]

Guidance literature:: With NaOAc; benzaldehyde; In dichloromethane; under N2 atm. AcONa, (IrCl2Cp*)2, imine, and benzaldehyde in CH2Cl2 werestirred for 5 h; soln. was filtered and evapd. to dryness, residue was washed with hexane; elem. anal.;
DOI:10.1039/b303737a

Reference yield:

: 12354-84-6,12354-85-7
bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]

: 538-51-2
benzylidene phenylamine

: 674800-06-7
[IrCl2(NH2Ph)(η-C5Me5)]

: 674800-05-6
[IrCl(C6H4-2-C(H)=NPh-κC,N)(η-C5Me5)]

Guidance literature:: With NaOAc; In dichloromethane; under N2 atm. AcONa, (IrCl2Cp*)2, and imine in CH2Cl2 were stirred for 5h;
DOI:10.1039/b303737a

Reference yield: 65.0%

: 17084-13-8
potassium hexafluorophosphate

: 674800-05-6
[IrCl(C6H4-2-C(H)=NPh-κC,N)(η-C5Me5)]

: 536-74-3
phenylacetylene

: 1259203-23-0
(C₅(CH₃)5)Ir(CHC₆H₅CCC₆H₅CHC₆H₄CHNC₆H₅)⁽¹⁺⁾*PF₆^(1-)=(C₅(CH₃)5)Ir(CHC₆H₅CCC₆H₅CHC₆H₄CHNC₆H₅)(PF₆)

Guidance literature:: In dichloromethane; (N2) alkyne and KPF6 were added to a soln. of complex in CH3CN, stirred for 7 h, CH3CN was replaced by CH2Cl2, the soln. was stirred for 21 h; evapd., the solid was washed through a small plug of silica (CH2Cl2/NCCH3), evapd.; elem. anal.;
DOI:10.1039/c0dt00280a