bis(triphenylphosphine)palladium acetate

Base Information

• Chemical Name: bis(triphenylphosphine)palladium acetate
• CAS No.: 61425-87-4
• Molecular Formula: C₄₀H₃₆O₄P₂Pd
• Molecular Weight: 749.091
• Mol file: 61425-87-4.mol

Synonyms:

Chemical Property of bis(triphenylphosphine)palladium acetate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of bis(triphenylphosphine)palladium acetate

There total 7 articles about bis(triphenylphosphine)palladium acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

palladium diacetate (3375-31-3) + triphenylphosphine (603-35-0) → bis(triphenylphosphine)palladium acetate (61425-87-4,70096-12-7,14588-08-0)

Guidance literature:

In methanol; (N2), Pd acetate in CH3OH treated with PPh3, stirred for 5 min at room temp.; evapd.(vac.), washed twice (Et2O), dried, NMR;

DOI:10.1016/j.molcata.2006.05.052

Reference yield: 56.0%

(CH3)2NCH2C(CH3)2CH2Pd(CH3CO2)2Pd(CH3CO2)2PdCH2C(CH3)2CH2N(CH3)2*0.5C6H6 → bis(triphenylphosphine)palladium acetate (61425-87-4,70096-12-7,14588-08-0) + Pd(CH2C(CH3)2CH2N(CH3)2)(CH3CO2)(P(C6H5)3)

Guidance literature:

With triphenylphosphine;

DOI:10.1016/0022-328X(85)88104-3

Reference yield:

palladium diacetate (3375-31-3) + triphenylphosphine (603-35-0) → bis(acetato)bis(triphenylphosphine)palladium(0) (70096-12-7,61425-87-4,14588-08-0)

Guidance literature:

In N,N-dimethyl-formamide; at 100 ℃; for 0.166667 - 0.25h; Product distribution / selectivity;

upstream raw materials:

palladium diacetate

triphenylphosphine

palladium diacetate

Downstream raw materials:

[Pd(O₂CCH₃)2(P(C₆H₅)3)]2

bis(triphenylphosphine)palladium⁽⁰⁾

cis-[Pd(oxalato)(triphenylphosphine)2]

palladium