[Rh2(CO)2Cl2((tert-butyl)NP(OC6H4OMe-o))2-κP)]2

Base Information

Chemical Name:[Rh2(CO)2Cl2((tert-butyl)NP(OC6H4OMe-o))2-κP)]2
CAS No.:862846-66-0
Molecular Formula:C₄₈H₆₄Cl₄N₄O₁₂P₄Rh₄
Molecular Weight:1566.38
Hs Code.:

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Chemical Property of [Rh2(CO)2Cl2((tert-butyl)NP(OC6H4OMe-o))2-κP)]2

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Technology Process of [Rh2(CO)2Cl2((tert-butyl)NP(OC6H4OMe-o))2-κP)]2

There total 2 articles about [Rh2(CO)2Cl2((tert-butyl)NP(OC6H4OMe-o))2-κP)]2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: di(rhodium)tetracarbonyl dichloride

: 862609-09-4
cis-[(o-MeOC6H4O)P(μ-Nt-Bu)]2

: 862846-66-0
[Rh2(CO)2Cl2((tert-butyl)NP(OC6H4OMe-o))2-κP)]2

Guidance literature:: In acetonitrile; using Schlenk techniques; reflux of mixt. of (RhCl(CO)2)2 (1 equiv.) andcis-((t-Bu)NP(OC6H4OMe-o))2 (1 equiv.) in MeCN with stirring for 4 h; evapn. under reduced pressure, twice washing with Et2O, elem. anal.;
DOI:10.1021/om0502537

Reference yield:

: di(rhodium)tetracarbonyl dichloride

: 862846-68-2
trans-[Rh(CO)Cl(cis-((o-MeOC6H4O)P(μ-NtBu))2-κP)2]

: 862846-66-0
[Rh2(CO)2Cl2((tert-butyl)NP(OC6H4OMe-o))2-κP)]2

Guidance literature:: In chloroform-d1; treatment of (Rh(CO)Cl(((tert-butyl)NP(OC6H4OMe-o))2-κP)2) with 1.5 equiv. of (Rh(CO)2Cl)2 in CDCl3; monitoring by NMR;
DOI:10.1021/om0502537

Reference yield:

: 862609-09-4
cis-[(o-MeOC6H4O)P(μ-Nt-Bu)]2

: 862846-66-0
[Rh2(CO)2Cl2((tert-butyl)NP(OC6H4OMe-o))2-κP)]2

: 862846-68-2
trans-[Rh(CO)Cl(cis-((o-MeOC6H4O)P(μ-NtBu))2-κP)2]

Guidance literature:: In chloroform-d1; treatment of (Rh2(CO)2Cl2(((tert-butyl)NP(OC6H4OMe-o))2-κP))2 with6 equiv. of cis-((tert-butyl)NP(OC6H4OMe-o))2 in CDCl3 for 1 h; monitoring by NMR;
DOI:10.1021/om0502537