trans-[Rh(CO)Cl(cis-((o-MeOC6H4O)P(μ-NtBu))2-κP)2]

Base Information

Chemical Name:trans-[Rh(CO)Cl(cis-((o-MeOC6H4O)P(μ-NtBu))2-κP)2]
CAS No.:862846-68-2
Molecular Formula:C₄₅H₆₄ClN₄O₉P₄Rh
Molecular Weight:1067.28
Hs Code.:

Synonyms:

Suppliers and Price of trans-[Rh(CO)Cl(cis-((o-MeOC6H4O)P(μ-NtBu))2-κP)2]

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of trans-[Rh(CO)Cl(cis-((o-MeOC6H4O)P(μ-NtBu))2-κP)2]

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of trans-[Rh(CO)Cl(cis-((o-MeOC6H4O)P(μ-NtBu))2-κP)2]

There total 2 articles about trans-[Rh(CO)Cl(cis-((o-MeOC6H4O)P(μ-NtBu))2-κP)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: di(rhodium)tetracarbonyl dichloride

: 862609-09-4
cis-[(o-MeOC6H4O)P(μ-Nt-Bu)]2

: 862846-68-2
trans-[Rh(CO)Cl(cis-((o-MeOC6H4O)P(μ-NtBu))2-κP)2]

Guidance literature:: In dichloromethane; using Schlenk techniques; addn. of soln. of (RhCl(CO)2)2 (1 equiv.) in CH2Cl2 to well-stirred soln. of cis-((t-Bu)NP(OC6H4OMe-o))2 (4 equiv.) inCH2Cl2 at room temp.; stirring for 4 h; concn. under reduced pressure, dilution with hexane, crystn. at room temp. for a day, elem. anal.;
DOI:10.1021/om0502537

Reference yield:

: 862609-09-4
cis-[(o-MeOC6H4O)P(μ-Nt-Bu)]2

: 862846-66-0
[Rh2(CO)2Cl2((tert-butyl)NP(OC6H4OMe-o))2-κP)]2

: 862846-68-2
trans-[Rh(CO)Cl(cis-((o-MeOC6H4O)P(μ-NtBu))2-κP)2]

Guidance literature:: In chloroform-d1; treatment of (Rh2(CO)2Cl2(((tert-butyl)NP(OC6H4OMe-o))2-κP))2 with6 equiv. of cis-((tert-butyl)NP(OC6H4OMe-o))2 in CDCl3 for 1 h; monitoring by NMR;
DOI:10.1021/om0502537

Reference yield: 93.0%

: 29892-37-3
chloro(dimethylsulfide) gold(I)

: 862846-68-2
trans-[Rh(CO)Cl(cis-((o-MeOC6H4O)P(μ-NtBu))2-κP)2]

: 1092707-00-0
trans-[Rh(CO)Cl(μ-cis-((o-MeOC6H4O)P(μ-NtBu))2-κP,κP)2(AuCl)2]

Guidance literature:: In dichloromethane; acetonitrile; anaerobic conditions, high-vac., Schlenk techniques; soln. of AuClSMe2 (0.187 mmol) in CH2Cl2 added dropwise to suspn. of Rh complex (0.093 mmol) in CH3CN at room temp.; mixt. stirred for 4 h; concd. under vac.; hexane added; stored overnight; elem. anal.;
DOI:10.1002/ejic.200700554