[Pd(eta.3-CH₃CHCHCHPh)(1,2-bis(diphenylphosphino)ethane)][PF₆]

Base Information

• Chemical Name: [Pd(eta.3-CH₃CHCHCHPh)(1,2-bis(diphenylphosphino)ethane)][PF₆]
• CAS No.: 869639-48-5
• Molecular Formula: C₃₆H₃₅P₂Pd*F₆P
• Molecular Weight: 781.006
• Mol file: 869639-48-5.mol

Synonyms:

Chemical Property of [Pd(eta.3-CH₃CHCHCHPh)(1,2-bis(diphenylphosphino)ethane)][PF₆]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Pd(eta.3-CH₃CHCHCHPh)(1,2-bis(diphenylphosphino)ethane)][PF₆]

There total 1 articles about [Pd(eta.3-CH₃CHCHCHPh)(1,2-bis(diphenylphosphino)ethane)][PF₆] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.7%

silver(I) hexafluorophosphate (26042-63-7) + (-)-(1S,2R,3R)-di-μ-chloro-bis(1-methyl-3-phenyl-π-allyl)dipalladium (88155-41-3,88076-44-2,165876-46-0) + 1,2-bis-(diphenylphosphino)ethane (1663-45-2) → [Pd(eta.3-CH3CHCHCHPh)(1,2-bis(diphenylphosphino)ethane)][PF6] (869639-48-5)

Guidance literature:

In dichloromethane; acetone; byproducts: AgCl; mixt. of AgPF6 (2 equiv.) and Pd complex (1 equiv.) placed under vac. and purged with N2; acetone added; mixt. stirred under N2 for 2 h; filtered through Celite; soln. of P ligand (2 equiv.) in CH2Cl2 added to filtrate under N2; soln. stirred for 1 h; filtered through Celite; rinsed with CH2Cl2; evapd. under vac.;

DOI:10.1021/om0505514

upstream raw materials:

silver(I) hexafluorophosphate

(-)-(1S,2R,3R)-di-μ-chloro-bis(1-methyl-3-phenyl-π-allyl)dipalladium

1,2-bis-(diphenylphosphino)ethane