RuI₂(C₁₁H₉N₃)2

Base Information

Chemical Name:RuI₂(C₁₁H₉N₃)2
CAS No.:77341-75-4
Molecular Formula:C₂₂H₁₈I₂N₆Ru
Molecular Weight:721.304
Hs Code.:

RuI<sub>2</sub>(C<sub>11</sub>H<sub>9</sub>N<sub>3</sub>)2

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of RuI₂(C₁₁H₉N₃)2

Chemical Property:

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Technology Process of RuI₂(C₁₁H₉N₃)2

There total 1 articles about RuI₂(C₁₁H₉N₃)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

: 2569-57-5
2-(phenylazo)pyridine

: 14898-67-0
ruthenium(III) chloride trihydrate

: 7681-82-5,24359-64-6,41927-88-2,115813-40-6
sodium iodide

: 77341-75-4
diiodobis(2-(phenylazo)pyridine)ruthenium(II)

Guidance literature:: In methanol; N2 was passed for 15 min through soln. of RuCl3*3H2O in MeOH, NaI was added, mixt. was stirred for 45 min at room temp., soln. of ligand in MeOH was added, mixt. was stirred for 8 h; filtered, washed with H2O and Et2O, dried in vac. desiccator over P4O10, ppt. was dissolved in CHCl3, chromy. on silica gel column, eluted withC6H6, evapd. at room temp.; elem. anal.;
DOI:10.1021/ic50221a061

Reference yield: 60.0%

: 77341-75-4
RuI₂(C₁₁H₉N₃)2

: sodium perchlorate

: 1486-28-8
diphenyl(methyl)phosphine

: 81554-70-3
iodo(diphenylmethylphosphine)bis[2-(phenylazo)pyridine]ruthenium(II) perchlorate hydrate

Guidance literature:: In methanol; water; PPh2Me was added to a suspn. of complex in 1:1 methanol-water mixture, refluxed for 4 h, poured a filtered soln. into aq. NaClO4 and kept in the refrigerator for 2-3 h; filtration, washing a ppt. with water and diethyl ether, drying over P4O10 in vac., column chromy. (silica gel, benzene-acetonitrile, 9:1, then3:2); elem. anal.;
DOI:10.1021/ic00137a040