Technology Process of phenylosazone of 1-deoxy-D-erythro-2,3-hexodiulose
There total 8 articles about phenylosazone of 1-deoxy-D-erythro-2,3-hexodiulose which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
Multi-step reaction with 5 steps
1: 65 percent / ruthenium dioxide, potassium periodate, potassium carbonate / CHCl3; H2O / 19 h
2: 79 percent / triethylamine, p-toluenesulfonic acid / 30 h / 70 °C / Heating
3: 65 percent / hydrogen / 10 percent palladium-on-charcoal / acetone; ethanol / 10 h / 25 °C / 760 Torr
4: Amberlite IR-120 cation-exchange resin, H(1+) form / H2O / 2 h / 60 °C / Heating
5: sodium acetate / H2O / Ambient temperature
With
ruthenium(IV) oxide; potassium metaperiodate; Amberlite IR-120 cation-exchange resin; hydrogen; sodium acetate; hydrogen cation; potassium carbonate; toluene-4-sulfonic acid; triethylamine;
palladium on activated charcoal;
In
ethanol; chloroform; water; acetone;
DOI:10.1016/0008-6215(83)88110-5
- Guidance literature:
-
Multi-step reaction with 4 steps
1: 79 percent / triethylamine, p-toluenesulfonic acid / 30 h / 70 °C / Heating
2: 65 percent / hydrogen / 10 percent palladium-on-charcoal / acetone; ethanol / 10 h / 25 °C / 760 Torr
3: Amberlite IR-120 cation-exchange resin, H(1+) form / H2O / 2 h / 60 °C / Heating
4: sodium acetate / H2O / Ambient temperature
With
Amberlite IR-120 cation-exchange resin; hydrogen; sodium acetate; hydrogen cation; toluene-4-sulfonic acid; triethylamine;
palladium on activated charcoal;
In
ethanol; water; acetone;
DOI:10.1016/0008-6215(83)88110-5
- Guidance literature:
-
Multi-step reaction with 3 steps
1: 65 percent / hydrogen / 10 percent palladium-on-charcoal / acetone; ethanol / 10 h / 25 °C / 760 Torr
2: Amberlite IR-120 cation-exchange resin, H(1+) form / H2O / 2 h / 60 °C / Heating
3: sodium acetate / H2O / Ambient temperature
With
Amberlite IR-120 cation-exchange resin; hydrogen; sodium acetate; hydrogen cation;
palladium on activated charcoal;
In
ethanol; water; acetone;
DOI:10.1016/0008-6215(83)88110-5
