Bis<4-(4,7,10,13-tetraoxa-1-azacyclopentadecyl)phenyl>diazen-N-oxid

Base Information

• Chemical Name: Bis<4-(4,7,10,13-tetraoxa-1-azacyclopentadecyl)phenyl>diazen-N-oxid
• CAS No.: 66769-99-1
• Molecular Formula: C₃₂H₄₈N₄O₉
• Molecular Weight: 632.755
• Mol file: 66769-99-1.mol

Synonyms:

Chemical Property of Bis<4-(4,7,10,13-tetraoxa-1-azacyclopentadecyl)phenyl>diazen-N-oxid

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Bis<4-(4,7,10,13-tetraoxa-1-azacyclopentadecyl)phenyl>diazen-N-oxid

There total 3 articles about Bis<4-(4,7,10,13-tetraoxa-1-azacyclopentadecyl)phenyl>diazen-N-oxid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

13-phenyl-1,4,7,10-tetraoxa-13-aza-cyclopentadecane (66750-10-5) → Bis<4-(4,7,10,13-tetraoxa-1-azacyclopentadecyl)phenyl>diazen-N-oxid (66769-99-1)

Guidance literature:

Multi-step reaction with 2 steps

1: 83 percent / 37percent HCl, NaNO₂ / H₂O / 20 h / temp. below 5 deg C

2: 1.) LiAlH₄, 2.) H₂O / 1.) THF, 1 h, 2.) THF

With hydrogenchloride; lithium aluminium tetrahydride; water; sodium nitrite; In water;

Reference yield:

2,2'-(phenylimino)bis[ethanol] (120-07-0) → Bis<4-(4,7,10,13-tetraoxa-1-azacyclopentadecyl)phenyl>diazen-N-oxid (66769-99-1)

Guidance literature:

Multi-step reaction with 3 steps

1: 16 percent / NaOH / dioxane / 30 h / Heating

2: 83 percent / 37percent HCl, NaNO₂ / H₂O / 20 h / temp. below 5 deg C

3: 1.) LiAlH₄, 2.) H₂O / 1.) THF, 1 h, 2.) THF

With hydrogenchloride; sodium hydroxide; lithium aluminium tetrahydride; water; sodium nitrite; In 1,4-dioxane; water;

Reference yield:

13-(4-nitrosophenyl)-1,4,7,10-tetraoxa-13-azacyclopentadecane (66750-07-0) → Bis<4-(4,7,10,13-tetraoxa-1-azacyclopentadecyl)phenyl>diazen (73171-30-9) + Bis<4-(4,7,10,13-tetraoxa-1-azacyclopentadecyl)phenyl>diazen-N-oxid (66769-99-1)

Guidance literature:

With lithium aluminium tetrahydride; water; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts; 1.) THF, 1 h, 2.) THF;

upstream raw materials:

13-(4-nitrosophenyl)-1,4,7,10-tetraoxa-13-azacyclopentadecane

2,2'-(phenylimino)bis[ethanol]

13-phenyl-1,4,7,10-tetraoxa-13-aza-cyclopentadecane