cis-{Ru(4-CH₃C₆H₄N=NH)2(PhP(OEt)2)4}(BPh₄)2

Base Information

Chemical Name:cis-{Ru(4-CH₃C₆H₄N=NH)2(PhP(OEt)2)4}(BPh₄)2
CAS No.:123753-06-0
Molecular Formula:2C₂₄H₂₀B*C₅₄H₇₆N₄O₈P₄Ru
Molecular Weight:1772.65
Hs Code.:

cis-{Ru(4-CH<sub>3</sub>C<sub>6</sub>H<sub>4</sub>N=NH)2(PhP(OEt)2)4}(BPh<sub>4</sub>)2

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Chemical Property of cis-{Ru(4-CH₃C₆H₄N=NH)2(PhP(OEt)2)4}(BPh₄)2

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Technology Process of cis-{Ru(4-CH₃C₆H₄N=NH)2(PhP(OEt)2)4}(BPh₄)2

There total 1 articles about cis-{Ru(4-CH₃C₆H₄N=NH)2(PhP(OEt)2)4}(BPh₄)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 123877-52-1,38619-44-2,38720-14-8
RuH₂(PPh(OEt)2)4

: 459-44-9
4-methylbenzenediazonium tetrafluoroborate

: 143-66-8
sodium tetraphenyl borate

: 123753-06-0
cis-{Ru(4-CH₃C₆H₄N=NH)2(PhP(OEt)2)4}(BPh₄)2

: 123752-93-2
{Ru(4-CH₃C₆H₄NNH)(PhP(OEt)2)4}(BPh₄)2

Guidance literature:: With ethanol or methanol; In dichloromethane; under H2 and/or Ar, quickly addn. of a soln. of Ru-complex in CHCl2 (cooled to -80°C) to the diazonium salt, warmed to room temp., stirred for 3 h, filtered, evapn., yellow oil treated with EtOH (or MeOH), addn. of NaBPh4, pptn.; filtered, recrystn. from CH2Cl2 and EtOH or MeOH;

Reference yield:

: 123753-06-0
cis-{Ru(4-CH₃C₆H₄N=NH)2(PhP(OEt)2)4}(BPh₄)2

: 121-44-8
triethylamine

: 123753-10-6
{Ru(4-CH₃C₆H₄N=NH)(PhP(OEt)2)4}BPh₄

Guidance literature:: With ethanol or methanol; In dichloromethane; under H2 and/or Ar, addn. of NEt3 to the Ru-complex in CHCl2, stirred for 2 h, after 30 min pptn. of a white solid, evapn. to dryness, resuting oi treated with EtOH (or MeOH), give a yellow soln., cooled to -4°C, pptn.; filtered, cooling to -30°C;