[Mo(CO)4(Ph₂PCH(butyl)PPh₂)]

Base Information

• Chemical Name: [Mo(CO)4(Ph₂PCH(butyl)PPh₂)]
• CAS No.: 1001401-05-3
• Molecular Formula: C₃₃H₃₀MoO₄P₂
• Molecular Weight: 648.486
• Mol file: 1001401-05-3.mol

Synonyms:

Chemical Property of [Mo(CO)4(Ph₂PCH(butyl)PPh₂)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Mo(CO)4(Ph₂PCH(butyl)PPh₂)]

There total 1 articles about [Mo(CO)4(Ph₂PCH(butyl)PPh₂)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

1-iodo-butane (542-69-8) + tetracarbonyl-bis(diphenylphosphino)methane-molybdenum(0) (26743-81-7) → [Mo(CO)4(Ph2PCH(butyl)PPh2)] (1001401-05-3)

Guidance literature:

With n-C₄H₉Li; In tetrahydrofuran; (N2); addn. of n-BuLi to Mo(CO)4(PPh2CH2PPh2) in THF; stirring for 30 min; addn. of BuI; stirring overnight; removal of volatiles; dissolving in CH2Cl2; washing with H2O; drying of CH2Cl2 portion over MgSO4; pumping down; dissolving in min. amt. of CH2Cl2; addn. a little MeOH; crystn.; elem. anal.;

DOI:10.1016/j.jorganchem.2007.09.024

Reference yield: 68.0%

[Mo(CO)4(Ph2PCH(butyl)PPh2)] (1001401-05-3) + methyllithium (917-54-4) + methyl iodide (74-88-4) → [Mo(CO)4(Ph2PCMe(butyl)PPh2)] (1001401-08-6)

Guidance literature:

In tetrahydrofuran; diethyl ether; (N2); addn. of soln. of MeLi in Et2O to soln. of Mo(CO)4(Ph2PCH(Bu)PPh2)in THF; stirring for 1 h; addn. of MeI; stirring for 3 ds; removal of volatiles, dissolving in CH2Cl2; washing with H2O; drying of CH2Cl2 portion over MgSO4; filtration, layering concd. CH2Cl2 soln. withMeOH; slow mixing; slow evapn., crystn.; elem. anal.;

DOI:10.1016/j.jorganchem.2007.09.024

upstream raw materials:

1-iodo-butane

tetracarbonyl-bis(diphenylphosphino)methane-molybdenum⁽⁰⁾

Downstream raw materials:

[Mo(CO)4(Ph₂PCMe(butyl)PPh₂)]