mer-tricarbonyldiiodo(triphenylphosphane)iron(II)

Base Information

Chemical Name:mer-tricarbonyldiiodo(triphenylphosphane)iron(II)
CAS No.:62075-68-7
Molecular Formula:C₂₁H₁₅FeI₂O₃P
Molecular Weight:655.978
Hs Code.:

Synonyms:

Suppliers and Price of mer-tricarbonyldiiodo(triphenylphosphane)iron(II)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of mer-tricarbonyldiiodo(triphenylphosphane)iron(II)

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of mer-tricarbonyldiiodo(triphenylphosphane)iron(II)

There total 3 articles about mer-tricarbonyldiiodo(triphenylphosphane)iron(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 15616-56-5,14911-55-8,14878-30-9
diiodotetracarbonyliron(II)

: 603-35-0
triphenylphosphine

: 15530-61-7,51744-71-9,62075-68-7
mer-tricarbonyldiiodo(triphenylphosphane)iron(II)

Guidance literature:: In hexane; (N2), in the dark; soln. of PPh3 in hexane added to soln. of iron complex in hexane, mixt. stirred at room temp.for 1 h; J. Inorg. Nucl. Chem. 1966, 28, 511-520; J. Organomet. Chem. 1977, 125, 231-252; J. Organomet. Chem. 2006, 691, 3881-3888; evapn. under vac., residue washed with hexane, dried under vac.; elem. anal.;
DOI:10.1021/ic9017882

Reference yield: 93.0%

: 15616-56-5,14911-55-8,14878-30-9
diiodotetracarbonyliron(II)

: 603-35-0
triphenylphosphine

: 15530-61-7,51744-71-9,62075-68-7
FeI₂(CO)₃PPh₃

Guidance literature:: In diethyl ether; -40°C to room temp., 1:1 or 1:2 ratio of educts; recrystn. from acetone/water;
DOI:10.1039/DT9730002103 DOI:10.1016/0022-1902(66)80332-9 DOI:10.1039/J19700000634

Reference yield:

: 15616-56-5,14911-55-8,14878-30-9
diiodotetracarbonyliron(II)

: 603-35-0
triphenylphosphine

: 14741-34-5,21255-52-7
tricarbonyl bis(triphenylphosphine) iron

: 911420-34-3
iron(II)(carbonyl)2((phenyl)3phosphine)2I₂

: 62075-68-7
fac-Fe(CO)3I₂(PPh₃)

Guidance literature:: In toluene; byproducts: (P(C6H5)3I)I; under N2 atm. using Schlenk techniques; Fe complex dissolved in toluene;soln. injected in thermostatted and blackened reactor (temp. was from - 40 to 25°C); phosphine (1.5E-1 to E-2 M) added; not isolated; monitored by IR spectroscopy;
DOI:10.1016/j.jorganchem.2006.05.041