MnH(CO)2(P(OC₆H₅)3)3

Base Information

• Chemical Name: MnH(CO)2(P(OC₆H₅)3)3
• CAS No.: 350580-18-6
• Molecular Formula: C₅₆H₄₆MnO₁₁P₃
• Molecular Weight: 1042.83
• Mol file: 350580-18-6.mol

Synonyms:

Chemical Property of MnH(CO)2(P(OC₆H₅)3)3

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of MnH(CO)2(P(OC₆H₅)3)3

There total 1 articles about MnH(CO)2(P(OC₆H₅)3)3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 35.0%

triphenyl phosphite (101-02-0) + pentacarbonylhydridomanganese (16972-33-1) → HMn(CO)3{P(C6H5O)3}2 (16972-18-2,16923-76-5,17250-37-2) + MnH(CO)2(P(OC6H5)3)3 (350580-18-6)

Guidance literature:

In toluene; Irradiation (UV/VIS); a soln. of complex in toluene was treated under Ar with an excess of phosphite, the mixt. was irradiated for 48 h at room temp. (400 W, Hg-lamp); the solvent was removed, the oil was chromd. on silica gel column (petroleum ether-benzene); elem. anal.;

DOI:10.1016/S0022-328X(00)00943-8

Reference yield: 85.0%

MnH(CO)2(P(OC6H5)3)3 (350580-18-6) + sodium tetraphenyl borate (143-66-8) + 4,4'-diphenylbisdiazonium ditetrafluoroborate → (Mn(CO)2(P(OC6H5)3)3)2HN2C6H4C6H4N2H(2+)*2B(C6H5)4(1-)=(Mn(CO)2(P(OC6H5)3)3)2N2HC6H4C6H4N2H(B(C6H5)4)2

Guidance literature:

In not given; solid samples of complex and bis(aryldiazonium) salt were cooled to =196°C, acetone or a mixt. acetone-CH2Cl2 (1:1) was slowly added, themixt. was stirred for 4 h, evapd., treated with ethanol, excess of NaBP h4 was added (inert atm.); cooled to -25°C, the solid was filtered, crystd. from Ch2Cl2-ethanol; elem. anal.;

DOI:10.1016/S0022-328X(00)00943-8

Reference yield: 80.0%

MnH(CO)2(P(OC6H5)3)3 (350580-18-6) + benzenediazonium tetrafluoroborate (369-57-3) + sodium tetraphenyl borate (143-66-8) → MnC6H5NNH(CO)2(P(OC6H5)3)3(1+)*B(C6H5)4(1-)=Mn(C6H5NNH)(CO)2(P(OC6H5)3)3(B(C6H5)4)

Guidance literature:

In dichloromethane; CH2Cl2 was added to a mixt. of complex and diazonium salt, the mixt. wasstirred for 2 h at room temp., evapd., treated with ethanol, NaBPh4 in ethanol was added (inert atm.); the soln. was cooled to -25°C, ppt. was filtered, crystd. from CH2Cl2-ethanol; elem. anal.;

DOI:10.1016/S0022-328X(00)00943-8

upstream raw materials:

triphenyl phosphite

pentacarbonylhydridomanganese