[RuCl(4'-(3-anisylphenyl)-2,2';6',2''-terpyridine)(2-mesityl-8-anisyl-1,10-phenanthroline)]PF₆

Base Information

• Chemical Name: [RuCl(4'-(3-anisylphenyl)-2,2';6',2''-terpyridine)(2-mesityl-8-anisyl-1,10-phenanthroline)]PF₆
• CAS No.: 862895-91-8
• Molecular Formula: C₅₆H₄₅ClN₅O₂Ru*F₆P
• Molecular Weight: 1101.49
• Mol file: 862895-91-8.mol

Synonyms:

Chemical Property of [RuCl(4'-(3-anisylphenyl)-2,2';6',2''-terpyridine)(2-mesityl-8-anisyl-1,10-phenanthroline)]PF₆

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [RuCl(4'-(3-anisylphenyl)-2,2';6',2''-terpyridine)(2-mesityl-8-anisyl-1,10-phenanthroline)]PF₆

There total 4 articles about [RuCl(4'-(3-anisylphenyl)-2,2';6',2''-terpyridine)(2-mesityl-8-anisyl-1,10-phenanthroline)]PF₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

potassium hexafluorophosphate (17084-13-8) + 8-anisyl-2-mesityl-1,10-phenanthroline (862694-14-2) + [RuCl3(4'-(3-anisylphenyl)-2,2';6',2''-terpyridine)] (879881-88-6) → Ru[(C5H4N)2C5H2NC6H4C6H4OCH3][(CH3OC6H4)C12H6N2((CH3)3C6H2)]Cl(1+)*PF6(1-)=(C56H45ClN5O2Ru)(PF6) (1002761-08-1,862895-91-8)

Guidance literature:

With triethylamine; lithium chloride; In ethanol; water; phenanthroline-compd. and Ru-compd. mixed together with an excess of LiCl and (C2H5)3N in a 1:4 water-ethanol mixture, heated to reflux for 4 h,saturated aq. KPF6 added; filtered, washed with water, precipitation of an acetone soln. into toluene and filtration and silica gel chromatography of the solid filtrate;

DOI:10.1039/b503411f

Reference yield:

[Ru(pyridine)(4'-(3-anisylphenyl)-2,2';6',2''-terpyridine)(2-mesityl-8-anisyl-1,10-phenanthroline)](PF6)2 + tetraethylammonium chloride (56-34-8) → [RuCl(4'-(3-anisylphenyl)-2,2';6',2''-terpyridine)(2-mesityl-8-anisyl-1,10-phenanthroline)]PF6 (1002761-08-1,862895-91-8) + [RuCl(4'-(3-anisylphenyl)-2,2';6',2''-terpyridine)(2-mesityl-8-anisyl-1,10-phenanthroline)]PF6 (1002761-08-1,862895-91-8)

Guidance literature:

In further solvent(s); soln. of Ru complex and Et4NCl in C2D2Cl4 in NMR tube was heated at 140°C for 2 h in dark;

DOI:10.1021/ic700734q

Reference yield:

[Ru(pyridine)(4'-(3-anisylphenyl)-2,2';6',2''-terpyridine)(2-mesityl-8-anisyl-1,10-phenanthroline)](PF6)2 + tetraethylammonium chloride (56-34-8) → [RuCl(4'-(3-anisylphenyl)-2,2';6',2''-terpyridine)(2-mesityl-8-anisyl-1,10-phenanthroline)]PF6 (1002761-08-1,862895-91-8) + [RuCl(4'-(3-anisylphenyl)-2,2';6',2''-terpyridine)(2-mesityl-8-anisyl-1,10-phenanthroline)]PF6 (1002761-08-1,862895-91-8)

Guidance literature:

In further solvent(s); soln. of Ru complex and Et4NCl in C2D2Cl4 in NMR tube was heated at 140°C for 2 h in dark;

DOI:10.1021/ic700734q

upstream raw materials:

potassium hexafluorophosphate

8-anisyl-2-mesityl-1,10-phenanthroline

[RuCl₃(4'-(3-anisylphenyl)-2,2';6',2''-terpyridine)]

tetraethylammonium chloride