trans-[Fe(N,N'-bis(2-isopropylphenyl)-2,3-butanediimine)2Cl₂]Cl

Base Information

• Chemical Name: trans-[Fe(N,N'-bis(2-isopropylphenyl)-2,3-butanediimine)2Cl₂]Cl
• CAS No.: 1148058-69-8
• Molecular Formula: C₄₄H₅₆Cl₂FeN₄*Cl
• Molecular Weight: 803.161
• Mol file: 1148058-69-8.mol

Synonyms:

Chemical Property of trans-[Fe(N,N'-bis(2-isopropylphenyl)-2,3-butanediimine)2Cl₂]Cl

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trans-[Fe(N,N'-bis(2-isopropylphenyl)-2,3-butanediimine)2Cl₂]Cl

There total 1 articles about trans-[Fe(N,N'-bis(2-isopropylphenyl)-2,3-butanediimine)2Cl₂]Cl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 26.0%

hydrogenchloride (7647-01-0,15364-23-5) + iron(II) chloride hexahydrate + N,N'-bis(2-isopropylphenyl)-2,3-butanediimine (49673-33-8) → trans-[Fe(N,N'-bis(2-isopropylphenyl)-2,3-butanediimine)2Cl2]Cl (1146746-22-6,1148058-69-8)

Guidance literature:

With H₂O₂; In ethanol; a soln. of diimine in ethanol was added dropwise to a soln. of Fe-salt in ethanol, the mixt. was stirred at room temp. for 2 h, 30% H2O2 was added dropwise, stirred for 1 h at room temp., 37% HCl was added, stirred for 1 h at room temp.; concd. by heating to 150°C, slow cooled to room temp., crystals were rinsed with ethanol and diethyl ether, dried in vac.;

DOI:10.1002/zaac.200700578

Reference yield: 47.0%

trans-[Fe(N,N'-bis(2-isopropylphenyl)-2,3-butanediimine)2Cl2]Cl (1146746-22-6,1148058-69-8) → cis-[Fe(N,N'-bis(2-isopropylphenyl)-2,3-butanediimine)2Cl2]Cl

Guidance literature:

In ethanol; a soln. of complex in min ethanol was gently evapd.; crystals were dried under vac.;

DOI:10.1002/zaac.200700578

upstream raw materials:

hydrogenchloride

N,N'-bis(2-isopropylphenyl)-2,3-butanediimine