9-(2-Phenylethyl)phenanthrene

Base Information

• Chemical Name: 9-(2-Phenylethyl)phenanthrene
• CAS No.: 106032-13-7
• Molecular Formula: C22H18
• Molecular Weight: 282.385
• DSSTox Substance ID: DTXSID00545128
• Wikidata: Q82422518
• Mol file: 106032-13-7.mol

Synonyms:9-(2-PHENYLETHYL)PHENANTHRENE;106032-13-7;DTXSID00545128

Chemical Property of 9-(2-Phenylethyl)phenanthrene

Chemical Property:

• XLogP3: 6.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 3
• Exact Mass: 282.140850574
• Heavy Atom Count: 22
• Complexity: 340

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)CCC2=CC3=CC=CC=C3C4=CC=CC=C42

Technology Process of 9-(2-Phenylethyl)phenanthrene

There total 14 articles about 9-(2-Phenylethyl)phenanthrene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + 9-iodo-phenanthrene (17024-12-3) → 1-(9-phenanthryl)-2-phenylethane (106032-13-7)

Guidance literature:

styrene; 9-iodo-phenanthrene; With sodium acetate; In N,N-dimethyl acetamide; at 100 ℃; Inert atmosphere;

With hydrogen; In N,N-dimethyl acetamide; at 20 ℃; under 760.051 Torr;

DOI:10.1002/adsc.200800460

Reference yield: 71.0%

9-(1-chloro-2-phenylethyl)phenanthrene (121221-37-2) → 1-(9-phenanthryl)-2-phenylethane (106032-13-7)

Guidance literature:

With sodium tetrahydroborate; In dimethyl sulfoxide; at 80 ℃;

DOI:10.1002/hlca.19880710707

Reference yield: 48.0%

1a,9b-dihydro-1a-(methylsulfinyl)-1H-cyclopropaphenanthrene → 9-methylphenanthrene (883-20-5) + 1,2-di(9-phenanthryl)ethane (22906-23-6) + 1-(9-phenanthryl)-2-phenylethane (106032-13-7) + 1,1'-(1,2-ethanediyl)bisbenzene (103-29-7)

Guidance literature:

With dihydrogen peroxide; In toluene; at 500 ℃; under 100 Torr;

DOI:10.1002/hlca.19860690412

upstream raw materials:

2-(9-phenanthryl)-1-phenylethanol

9-(1-chloro-2-phenylethyl)phenanthrene

diethyl ether

9-styryl-phenanthrene

Downstream raw materials:

1,1-dichloro-1a,9b-dihydro-1a-(2-phenylethyl)-1H-cyclopropa<1>phenanthrene

2-phenylcyclopenta[l]phenanthrene