dichloromonocyclopentadienyl[2-(2,3,4,5,6-pentafluoroanilino)tropone]titanium(IV)

Base Information

Chemical Name:dichloromonocyclopentadienyl[2-(2,3,4,5,6-pentafluoroanilino)tropone]titanium(IV)
CAS No.:868134-87-6
Molecular Formula:C₁₈H₁₀Cl₂F₅NOTi
Molecular Weight:470.062
Hs Code.:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of dichloromonocyclopentadienyl[2-(2,3,4,5,6-pentafluoroanilino)tropone]titanium(IV)

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Technology Process of dichloromonocyclopentadienyl[2-(2,3,4,5,6-pentafluoroanilino)tropone]titanium(IV)

There total 1 articles about dichloromonocyclopentadienyl[2-(2,3,4,5,6-pentafluoroanilino)tropone]titanium(IV) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 1270-98-0
cyclopentadienyl titanium(IV) trichloride

: 7732-18-5
water

: 259266-43-8
2-(2,3,4,5,6-pentafluoroanilino)tropone

: 868134-87-6
dichloromonocyclopentadienyl[2-(2,3,4,5,6-pentafluoroanilino)tropone]titanium(IV)

: (cyclopentadienyl)[2-(2,3,4,5,6-pentafluoroanilino)tropone]TiCl-O-TiCl₂(cyclopentadienyl)*(dichloromethane)

Guidance literature:: With n-BuLi; In tetrahydrofuran; under N2; n-BuLi added dropwise at -78°C to ligand in THF; stirred at -78°C for 1 h, then at room temp.; added dropwise to soln. of Ti complex in THF at -78°C; warmed slowly to ambient temp.; stirred for 1 h; solvent removed in vac.; dissolved in min. CH2Cl2; soln. filtered through Celite; layered with hexane; single crystals of Ti-Cl2 complex obtained; single crystals of Ti-Cl complex isolated as byproduct from CH2Cl2-pentane soln.; elem. anal.;
DOI:10.1039/b506079f