(C₅H₅)2Zr(OC₆H₅)(OCC₆H₅){W(CO)5}

Base Information

Chemical Name:(C₅H₅)2Zr(OC₆H₅)(OCC₆H₅){W(CO)5}
CAS No.:121253-42-7
Molecular Formula:C₂₈H₂₀O₇WZr
Molecular Weight:743.537
Hs Code.:

(C<sub>5</sub>H<sub>5</sub>)2Zr(OC<sub>6</sub>H<sub>5</sub>)(OCC<sub>6</sub>H<sub>5</sub>){W(CO)5}

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (C₅H₅)2Zr(OC₆H₅)(OCC₆H₅){W(CO)5}

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Technology Process of (C₅H₅)2Zr(OC₆H₅)(OCC₆H₅){W(CO)5}

There total 2 articles about (C₅H₅)2Zr(OC₆H₅)(OCC₆H₅){W(CO)5} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 14040-11-0
tungsten hexacarbonyl

: bis(η5-cyclopentadienyl)chlorophenoxyzirconium(IV)

: 591-51-5
phenyllithium

: 121253-42-7
(C₅H₅)2Zr(OC₆H₅)(OCC₆H₅){W(CO)5}

Guidance literature:: In diethyl ether; addn. of an ethereal soln. of C6H5Li to a suspn. of W(CO)6 in (C2H5)2O under Ar, stirring (ambient temp., 30 min), addn. of CH2Cl2, cooling (-78°C), addn. of Cp2Zr(OPh)Cl in toluene, stirring (-78°C, 2.5 h), warming to room temp.; removing of volatiles (vac.), pptn., decantation, dissolution of the product in benzene, filtration, addn. of heptane, reduction of soln. (vac.), pptn.; elem. anal.;
DOI:10.1021/om00110a034

Reference yield: 29.0%

: 14040-11-0
tungsten hexacarbonyl

: 51177-89-0
diphenyl dicyclopentadienyl-zirconium

: 108-95-2,27073-41-2
phenol

: 121253-42-7
(C₅H₅)2Zr(OC₆H₅)(OCC₆H₅){W(CO)5}

Guidance literature:: In n-heptane; stirring of a mixt. of diphenylzirconocene and W(CO)6 in heptane under Ar (90°C, 6 h), cooling to 50°C, addn. of phenol, stirring (5 min), filtration, keeping of the filtrate at -29°C (12 h), pptn., decantation; dissolution of the product in benzene, filtration, addn. of heptane, reduction of soln. (vac.), pptn.; elem. anal.;
DOI:10.1021/om00110a034

Reference yield:

: 121253-42-7
(C₅H₅)2Zr(OC₆H₅)(OCC₆H₅){W(CO)5}

: 19493-09-5
Methylenetriphenylphosphorane

: 121253-43-8
(C₅H₅)2Zr(OC₆H₅)(OC(C₆H₅)CH₂)

Guidance literature:: In benzene; byproducts: Cp2Zr(OPh)2, Cp2Zr{OC(Ph)CH2}2; addn. of Ph3PCH2 in benzene to the zirconoxycarbene complex in benzene (ambient temp.) under Ar, stirring (5 min), removing of volatiles (vac.), extn. of oily residue (pentane), filtration; pptn. from pentane at -78°C together with small amts. of Cp2Zr(OPh)2 and Cp2Zr(OC(C6H5)CH2)2;
DOI:10.1021/om00110a034