[(1,2-bis(di-tert-butylphosphino)ethane)Ni-NHAd][B(3,5-(CF₃)2C₆H₃)4]

Base Information

• Chemical Name: [(1,2-bis(di-tert-butylphosphino)ethane)Ni-NHAd][B(3,5-(CF₃)2C₆H₃)4]
• CAS No.: 1319198-79-2
• Molecular Formula: C₂₈H₅₆NNiP₂*C₃₂H₁₂BF₂₄
• Molecular Weight: 1390.62
• Mol file: 1319198-79-2.mol

Synonyms:

Chemical Property of [(1,2-bis(di-tert-butylphosphino)ethane)Ni-NHAd][B(3,5-(CF₃)2C₆H₃)4]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(1,2-bis(di-tert-butylphosphino)ethane)Ni-NHAd][B(3,5-(CF₃)2C₆H₃)4]

There total 2 articles about [(1,2-bis(di-tert-butylphosphino)ethane)Ni-NHAd][B(3,5-(CF₃)2C₆H₃)4] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

[(1,2-bis(di-tert-butylphosphino)ethane)Ni=NAd][B(3,5-(CF3)2C6H3)4] (1319198-81-6) → [(1,2-bis(di-tert-butylphosphino)ethane)Ni-NHAd][B(3,5-(CF3)2C6H3)4] (1319198-79-2)

Guidance literature:

In tetrahydrofuran; (N2) soln. Ni complex in THF was stirred at room temp. for 30 min; solvent was removed in vacuo; elem. anal.;

DOI:10.1021/ja2024993

Reference yield: 80.0%

ferrocenium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate (156301-37-0) + (1,2-bis(di-tert-butylphosphino)ethane)Ni=N-1-adamantyl (1058634-59-5) → [(1,2-bis(di-tert-butylphosphino)ethane)Ni-NHAd][B(3,5-(CF3)2C6H3)4] (1319198-79-2)

Guidance literature:

In diethyl ether; (N2) to Ni complex in Et2O at -35°C soln. (Cp2Fe)(BAr4) in Et2O was added, stirred for 1 h; soln. was dried in vacuo, residue was washed with petroleum ether, extd.with Et2O and layered with petroleum ether; elem. anal.;

DOI:10.1021/ja2024993

upstream raw materials:

ferrocenium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate

(1,2-bis(di-tert-butylphosphino)ethane)Ni=N-1-adamantyl

[(1,2-bis(di-tert-butylphosphino)ethane)Ni=NAd][B(3,5-(CF₃)2C₆H₃)4]