β-phenyl-510,5-tris(4-bromophenyl)subporphyrin

Base Information

• Chemical Name: β-phenyl-510,5-tris(4-bromophenyl)subporphyrin
• CAS No.: 1318254-72-6
• Molecular Formula: C₃₉H₂₃BBr₃N₃
• Molecular Weight: 784.155
• Mol file: 1318254-72-6.mol

Synonyms:

Chemical Property of β-phenyl-510,5-tris(4-bromophenyl)subporphyrin

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of β-phenyl-510,5-tris(4-bromophenyl)subporphyrin

There total 3 articles about β-phenyl-510,5-tris(4-bromophenyl)subporphyrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

β-methoxy-5,10,15-tris(4-bromophenyl)subporphyrinatoboron (III) + phenylmagnesium bromide (100-58-3) → β-phenyl-510,5-tris(4-bromophenyl)subporphyrin (1318254-72-6)

Guidance literature:

β-methoxy-5,10,15-tris(4-bromophenyl)subporphyrinatoboron (III); In 1,4-dioxane; at 100 ℃; for 0.166667h; Inert atmosphere;

phenylmagnesium bromide; In tetrahydrofuran; water; at 100 ℃; for 1h; Inert atmosphere; Cooling with ice;

DOI:10.1002/chem.201904151

Reference yield: 57.0%

(B(N3C15H6(C6H4Br)3))(1+)*HCB11H5Br6(1-)=(B(N3C15H6(C6H4Br)3))(HCB11H5Br6) + phenyllithium (591-51-5) → β-phenyl-510,5-tris(4-bromophenyl)subporphyrin (1318254-72-6)

Guidance literature:

In toluene; 0°C, 1 h;

DOI:10.1021/ja2056566

Reference yield:

β-methoxy-5,10,15-tris(4-bromophenyl)subporphyrinatoboron (III) → β-phenyl-510,5-tris(4-bromophenyl)subporphyrin (1318254-72-6)

Guidance literature:

β-methoxy-5,10,15-tris(4-bromophenyl)subporphyrinatoboron (III); In toluene; for 3h; Inert atmosphere; Darkness;

With phenyllithium; In diethyl ether; cyclohexane; toluene; at 0 ℃; for 0.5h; Inert atmosphere;

DOI:10.1021/ja2056566

upstream raw materials:

phenyllithium

phenylmagnesium bromide