3,4-bis(4'-terpyridyl-p-phenyl)-o-dicarbomethoxybenzene

Base Information

• Chemical Name: 3,4-bis(4'-terpyridyl-p-phenyl)-o-dicarbomethoxybenzene
• CAS No.: 1374792-56-9
• Molecular Formula: C₅₂H₃₆N₆O₄
• Molecular Weight: 808.896
• Mol file: 1374792-56-9.mol

Synonyms:

Chemical Property of 3,4-bis(4'-terpyridyl-p-phenyl)-o-dicarbomethoxybenzene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 3,4-bis(4'-terpyridyl-p-phenyl)-o-dicarbomethoxybenzene

There total 1 articles about 3,4-bis(4'-terpyridyl-p-phenyl)-o-dicarbomethoxybenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 51.0%

4′-(4-boronatophenyl)-2,2′:6′,2′′-terpyridine (381218-96-8) + dimethyl 4,5-dibromo-1,2-benzenedicarboxylate (859299-66-4) → 3,4-bis(4'-terpyridyl-p-phenyl)-o-dicarbomethoxybenzene (1374792-56-9)

Guidance literature:

With bis-triphenylphosphine-palladium(II) chloride; sodium carbonate; In water; toluene; tert-butyl alcohol; for 48h; Inert atmosphere; Reflux;

DOI:10.1021/ja303177v

Reference yield: 40.0%

dichlorotetrakis(dimethylsulfoxide)ruthenium(II) + 3,4-bis(4'-terpyridyl-p-phenyl)-o-dicarbomethoxybenzene (1374792-56-9) → Ru((CH3OOC)2C6H2(C6H4C5H2N(C5H4N)2)2)2(2+)*2PF6(1-)=[Ru((CH3OOC)2C6H2(C6H4C5H2N(C5H4N)2)2)2](PF6)2

Guidance literature:

In methanol; chloroform; mixt. of Ru complex and terpyridine deriv. in CHCl3/methanol (1/1) heated under reflux; chromy. (Al2O3, CHCl3 to CH3CN/H2O/satd. KNO3 (25/1/1)); NMR;

DOI:10.1021/ja303177v

Reference yield:

3,4-bis(4'-terpyridyl-p-phenyl)-o-dicarbomethoxybenzene (1374792-56-9) + 1,2,4,5-tetrakis(4'-terpyridyl-p-phenyl)-p-dihexoxybenzene + cadmium(II) (22537-48-0) → 6Cd(2+)*4(CH3OOC)2C6H2(C6H4C5H2N(C5H4N)2)2*(CH3(CH2)5O)2C6(C6H4C5H2N(C5H4N)2)4=C310H226N36O18Cd6(12+) + [Cd3((CH3OOC)2C6H2(C6H4C5H2N(C5H4N)2)2)3](6+)

Guidance literature:

In not given; Cd compd. (6 equiv.), tetra(terpyridine) (1 equiv.) and di(terpyridine) deriv. (4 equiv.); ESI-MS;

DOI:10.1021/ja303177v

upstream raw materials:

4′-(4-boronatophenyl)-2,2′:6′,2′′-terpyridine

dimethyl 4,5-dibromo-1,2-benzenedicarboxylate