Methyl (1'S,2'R,3'R,4'S)-(+)-2',3'-Bis(benzyloxymethyl)-4'-hydroxycyclohexylacetate

Base Information

Chemical Name:Methyl (1'S,2'R,3'R,4'S)-(+)-2',3'-Bis(benzyloxymethyl)-4'-hydroxycyclohexylacetate
CAS No.:151062-71-4
Molecular Formula:C₂₅H₃₂O₅
Molecular Weight:412.526
Hs Code.:

Synonyms:

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Chemical Property of Methyl (1'S,2'R,3'R,4'S)-(+)-2',3'-Bis(benzyloxymethyl)-4'-hydroxycyclohexylacetate

Chemical Property:

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Technology Process of Methyl (1'S,2'R,3'R,4'S)-(+)-2',3'-Bis(benzyloxymethyl)-4'-hydroxycyclohexylacetate

There total 7 articles about Methyl (1'S,2'R,3'R,4'S)-(+)-2',3'-Bis(benzyloxymethyl)-4'-hydroxycyclohexylacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 151062-62-3
(1S,2R,6R,7S,9S)-(+)-9-Hydroxy-4-oxatricyclo<5.2.2.0^2,6>undecan-3-one

: 151062-71-4
Methyl (1'S,2'R,3'R,4'S)-(+)-2',3'-Bis(benzyloxymethyl)-4'-hydroxycyclohexylacetate

Guidance literature:: Multi-step reaction with 6 steps

1: 98 percent / pyridinium p-toluenesulfonate / CH₂Cl₂ / 3 h / Ambient temperature

2: 98 percent / LiAlH₄ / tetrahydrofuran / 2.5 h / Ambient temperature

3: 1) NaH, 2) (nBu)4NI / 1) DMF, r.t., 1 h, 2) r.t., 4 h

4: 98 percent / p-toluenesulfonic acid monohydrate (p-TsOH) / methanol / 6 h / Ambient temperature

5: 82 percent / pyridinium dichromate / CH₂Cl₂ / 8 h / Ambient temperature

With lithium aluminium tetrahydride; dipyridinium dichromate; pyridinium p-toluenesulfonate; tetra-(n-butyl)ammonium iodide; sodium hydride; toluene-4-sulfonic acid; In tetrahydrofuran; methanol; dichloromethane;

Reference yield:

: (1S,2S,4S,5R,6R)-(+)-5,6-Bis(hydroxymethyl)-2-(tetrahydro-2H-pyran-2-yloxy)bicyclo<2.2.2>octane

: 151062-71-4
Methyl (1'S,2'R,3'R,4'S)-(+)-2',3'-Bis(benzyloxymethyl)-4'-hydroxycyclohexylacetate

Guidance literature:: Multi-step reaction with 4 steps

1: 1) NaH, 2) (nBu)4NI / 1) DMF, r.t., 1 h, 2) r.t., 4 h

2: 98 percent / p-toluenesulfonic acid monohydrate (p-TsOH) / methanol / 6 h / Ambient temperature

3: 82 percent / pyridinium dichromate / CH₂Cl₂ / 8 h / Ambient temperature

With dipyridinium dichromate; tetra-(n-butyl)ammonium iodide; sodium hydride; toluene-4-sulfonic acid; In methanol; dichloromethane;

Reference yield:

: (1S,2R,6S,7R,8R,9R)-(+)-9-Hydroxy-8-iodo-4-oxatricyclo<5.2.2.0^2,6>undec-3-one

: 151062-71-4
Methyl (1'S,2'R,3'R,4'S)-(+)-2',3'-Bis(benzyloxymethyl)-4'-hydroxycyclohexylacetate

Guidance literature:: Multi-step reaction with 7 steps

1: 94 percent / (nBu)3SnH / ethanol / 3 h / Ambient temperature

2: 98 percent / pyridinium p-toluenesulfonate / CH₂Cl₂ / 3 h / Ambient temperature

3: 98 percent / LiAlH₄ / tetrahydrofuran / 2.5 h / Ambient temperature

4: 1) NaH, 2) (nBu)4NI / 1) DMF, r.t., 1 h, 2) r.t., 4 h

5: 98 percent / p-toluenesulfonic acid monohydrate (p-TsOH) / methanol / 6 h / Ambient temperature

6: 82 percent / pyridinium dichromate / CH₂Cl₂ / 8 h / Ambient temperature

With lithium aluminium tetrahydride; dipyridinium dichromate; tri-n-butyl-tin hydride; pyridinium p-toluenesulfonate; tetra-(n-butyl)ammonium iodide; sodium hydride; toluene-4-sulfonic acid; In tetrahydrofuran; methanol; ethanol; dichloromethane;