(E)-3-(boronic acid pinacolate ester)-1-phenyl-1-nonene

Base Information

Chemical Name:(E)-3-(boronic acid pinacolate ester)-1-phenyl-1-nonene
CAS No.:1356468-03-5
Molecular Formula:C₂₁H₃₃BO₂
Molecular Weight:328.303
Hs Code.:

Synonyms:

Suppliers and Price of (E)-3-(boronic acid pinacolate ester)-1-phenyl-1-nonene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (E)-3-(boronic acid pinacolate ester)-1-phenyl-1-nonene

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (E)-3-(boronic acid pinacolate ester)-1-phenyl-1-nonene

There total 6 articles about (E)-3-(boronic acid pinacolate ester)-1-phenyl-1-nonene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 103-64-0,1340-14-3
bromostyrene

: 169339-75-7
(E)-2-(hept-1'-en-1'-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

: 1356468-03-5
(E)-3-(boronic acid pinacolate ester)-1-phenyl-1-nonene

Guidance literature:: With potassium fluoride; 6,6'-dimethyl-2,2'-bipyridine; Triethoxysilane; nickel(II) bromide 2-methoxyethyl ether complex; In N,N-dimethyl acetamide; acetonitrile; at 25 ℃; for 24h; regioselective reaction; Schlenk technique; Inert atmosphere;
DOI:10.1021/acs.orglett.0c02923

Reference yield:

: 16323-20-9
cinnamyl magnesium bromide

: 86308-26-1
2-hex-1-yl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

: (Z)-3-(boronic acid pinacolate ester)-1-phenyl-1-nonene

: 1356468-03-5
(E)-3-(boronic acid pinacolate ester)-1-phenyl-1-nonene

Guidance literature:: 2-hex-1-yl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane; With sec.-butyllithium; In tetrahydrofuran; dichloromethane; at -90 ℃; for 0.5h; Inert atmosphere;

With zinc(II) chloride; In tetrahydrofuran; dichloromethane; at -90 - 20 ℃; Inert atmosphere;

cinnamyl magnesium bromide; In tetrahydrofuran; at 0 - 20 ℃; Inert atmosphere;
DOI:10.1039/c2cc16076e

Reference yield:

: 628-71-7
1-Heptyne

: 1356468-03-5
(E)-3-(boronic acid pinacolate ester)-1-phenyl-1-nonene

Guidance literature:: Multi-step reaction with 2 steps

1: Schwartz's reagent; triethylamine / 24 h / 60 °C / Schlenk technique; Inert atmosphere

2: nickel(II) bromide 2-methoxyethyl ether complex; 6,6'-dimethyl-2,2'-bipyridine; potassium fluoride; Triethoxysilane / N,N-dimethyl acetamide; acetonitrile / 24 h / 25 °C / Schlenk technique; Inert atmosphere

With potassium fluoride; Schwartz's reagent; 6,6'-dimethyl-2,2'-bipyridine; Triethoxysilane; nickel(II) bromide 2-methoxyethyl ether complex; triethylamine; In N,N-dimethyl acetamide; acetonitrile;
DOI:10.1021/acs.orglett.0c02923