neopentyl N-toluenesulfonyl thioxocarbamate

Base Information

• Chemical Name: neopentyl N-toluenesulfonyl thioxocarbamate
• CAS No.: 175725-45-8
• Molecular Formula: C₁₃H₁₉NO₃S₂
• Molecular Weight: 301.431
• Mol file: 175725-45-8.mol

Synonyms:

Chemical Property of neopentyl N-toluenesulfonyl thioxocarbamate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of neopentyl N-toluenesulfonyl thioxocarbamate

There total 2 articles about neopentyl N-toluenesulfonyl thioxocarbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

2,2-dimethyl-propanol-1 (75-84-3) + p-tolylsulfonyl isothiocyanate (1424-52-8) → neopentyl N-toluenesulfonyl thioxocarbamate (175725-45-8)

Guidance literature:

In benzene; for 4h; Heating;

DOI:10.1016/0040-4020(95)01019-X

Reference yield:

toluene-4-sulfonamide (70-55-3) → neopentyl N-toluenesulfonyl thioxocarbamate (175725-45-8)

Guidance literature:

Multi-step reaction with 2 steps

1: 1.) KOH / 1.) reflux, 6 h, 2.) benzene, RT, overnight

2: 98 percent / benzene / 4 h / Heating

With potassium hydroxide; In benzene;

DOI:10.1016/0040-4020(95)01019-X

Reference yield: 79.0%

isobutyl vinyl ether (109-53-5,9003-44-5) + neopentyl N-toluenesulfonyl thioxocarbamate (175725-45-8) → tributintin p-toluenesulfinate (60199-13-5) + (1-Isobutoxy-ethyl)-thiocarbamic acid O-(2,2-dimethyl-propyl) ester

Guidance literature:

With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; Heating;

DOI:10.1016/0040-4020(95)01019-X

upstream raw materials:

2,2-dimethyl-propanol-1

p-tolylsulfonyl isothiocyanate

toluene-4-sulfonamide

Downstream raw materials:

tributintin p-toluenesulfinate

Refernces