Ir(CF₃SO₃)(CO)(PCH₃(C₆H₅)2)2

Base Information

Chemical Name:Ir(CF₃SO₃)(CO)(PCH₃(C₆H₅)2)2
CAS No.:138666-27-0
Molecular Formula:C₂₈H₂₆F₃IrO₄P₂S
Molecular Weight:769.741
Hs Code.:

Ir(CF<sub>3</sub>SO<sub>3</sub>)(CO)(PCH<sub>3</sub>(C<sub>6</sub>H<sub>5</sub>)2)2

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Chemical Property of Ir(CF₃SO₃)(CO)(PCH₃(C₆H₅)2)2

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Technology Process of Ir(CF₃SO₃)(CO)(PCH₃(C₆H₅)2)2

There total 1 articles about Ir(CF₃SO₃)(CO)(PCH₃(C₆H₅)2)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

: 15318-32-8,30669-24-0
trans-carbonylchlorobis(diphenylmethylphosphine)iridium(I)

: 2923-28-6
silver trifluoromethanesulfonate

: 138666-27-0
Ir(CF₃SO₃)(CO)(PCH₃(C₆H₅)2)2

Guidance literature:: In benzene; react. under dry N2, charging a Schlenk flask with trans-IrCl(CO)(PMePh2)2 and AgOTf, capping with a rubber septum, addn. of freshly distd., degassed benzene via cannula, stirring at room temp. for 2 h; filtration under N2, reducing the solvent, dropwise addn. of hexane, pptn., filtration, concg. the filtrate under vac., crystn., elem. anal.;

Reference yield: 75.0%

: 12120-15-9
ethylenebis(triphenylphosphine)platinum⁽⁰⁾

: 138666-27-0
Ir(CF₃SO₃)(CO)(PCH₃(C₆H₅)2)2

: {(PCH₃(C₆H₅)2)2(CO)Ir(H)(CHCH₂)Pt(P(C₆H₅)3)2}⁽¹⁺⁾*CF₃SO₃^(1-)={(PCH₃(C₆H₅)2)2(CO)Ir(H)(CHCH₂)Pt(P(C₆H₅)3)2}{CF₃SO₃}

Guidance literature:: In nitromethane; react. under dry N2, charging a Schlenk flask with trans-IrCl(OTf)(CO)(PMePh2)2 and Pt(H2CCH2)(PPh3)2, capping with a rubber septum, addn. of CH3NO2 via cannula, stirring at room temp. for 2 h; filtration under N2, no complete purifn. possible;

Reference yield: 73.0%

: 114455-47-9
Pt(C₂H₄)(1,3-bis(diphenylphosphino)propane)

: 138666-27-0
Ir(CF₃SO₃)(CO)(PCH₃(C₆H₅)2)2

: (PCH₃(C₆H₅)2)2COIrHC₂H₃Pt(C₆H₅)4P₂C₃H₆⁽¹⁺⁾*CF₃SO₃^(1-)*0.1C₄H₁₀O=(PCH₃(C₆H₅)2)2COIrHC₂H₃Pt(C₆H₅)4P₂C₃H₆CF₃SO₃*0.1(C₂H₅)2O

Guidance literature:: In nitromethane; react. under dry N2, charging a Schlenk flask with trans-IrCl(OTf)(PMePh2)2 and Pt(H2CCH2)(Ph2P(CH2)3PPh2), capping with a rubber septum, addn. of CH3NO2 via cannula, stirring at room temp. for 2 h; filtration under N2, vapor diffusion of diethyl ether into a concd. CH3NO3 soln., elem. anal.;