[Re2(μ-CO)(μ-Cl)(μ-dppm)2Cl2(CO)(2,6-dimethylphenyl isocyanide)]O3SCF3

Base Information

• Chemical Name: [Re2(μ-CO)(μ-Cl)(μ-dppm)2Cl2(CO)(2,6-dimethylphenyl isocyanide)]O3SCF3
• CAS No.: 184179-21-3
• Molecular Formula: CF₃O₃S*C₆₁H₅₃Cl₃NO₂P₄Re₂
• Molecular Weight: 1583.84
• Mol file: 184179-21-3.mol

Synonyms:

Chemical Property of [Re2(μ-CO)(μ-Cl)(μ-dppm)2Cl2(CO)(2,6-dimethylphenyl isocyanide)]O3SCF3

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Re2(μ-CO)(μ-Cl)(μ-dppm)2Cl2(CO)(2,6-dimethylphenyl isocyanide)]O3SCF3

There total 1 articles about [Re2(μ-CO)(μ-Cl)(μ-dppm)2Cl2(CO)(2,6-dimethylphenyl isocyanide)]O3SCF3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

[Re2Cl3(dppm)2(CO)(2,6-dimethylphenyl isocyanide)(NCCH3)]O3SCF3 + carbon monoxide (201230-82-2) → [Re2(μ-CO)(μ-Cl)(μ-dppm)2Cl2(CO)(2,6-dimethylphenyl isocyanide)]O3SCF3 (184179-21-3)

Guidance literature:

In dichloromethane; absence of air and moisture; purging CO for 5 min, then stirring at 25°C for 19 h; solvent removal, dissoln. in CH2Cl2, pptn. on Et2O addn., collection (filtration), drying; elem. anal.;

DOI:10.1021/ic9604831

upstream raw materials:

carbon monoxide