propargyl 2,3-di-O-benzyl-5-O-triisopropylsilyl-β-D-ribofuranoside

Base Information

• Chemical Name: propargyl 2,3-di-O-benzyl-5-O-triisopropylsilyl-β-D-ribofuranoside
• CAS No.: 1067674-97-8
• Molecular Formula: C₃₁H₄₄O₅Si
• Molecular Weight: 524.773
• Mol file: 1067674-97-8.mol

Synonyms:

Chemical Property of propargyl 2,3-di-O-benzyl-5-O-triisopropylsilyl-β-D-ribofuranoside

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of propargyl 2,3-di-O-benzyl-5-O-triisopropylsilyl-β-D-ribofuranoside

There total 1 articles about propargyl 2,3-di-O-benzyl-5-O-triisopropylsilyl-β-D-ribofuranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

p-tolyl 2,3-di-O-benzyl-1-thio-5-O-triisopropylsilyl-β-D-ribofuranoside (1067674-45-6) + propargyl alcohol (107-19-7) → propargyl 2,3-di-O-benzyl-5-O-triisopropanylsilyl-α-D-ribofuranoside (1067674-91-2) + propargyl 2,3-di-O-benzyl-5-O-triisopropylsilyl-β-D-ribofuranoside (1067674-97-8)

Guidance literature:

p-tolyl 2,3-di-O-benzyl-1-thio-5-O-triisopropylsilyl-β-D-ribofuranoside; propargyl alcohol; With strontium(II) carbonate; silver trifluoromethanesulfonate; In dichloromethane; at 20 ℃; for 0.25h; Molecular sieve;

With p-toluolsulfenyl bromide; In dichloromethane; 1,2-dichloro-ethane; at 0 ℃; for 0.0166667 - 0.25h; optical yield given as %de;

DOI:10.1021/jo801408x

upstream raw materials:

p-tolyl 2,3-di-O-benzyl-1-thio-5-O-triisopropylsilyl-β-D-ribofuranoside

propargyl alcohol